Bulletin of the Korean Chemical Society

  • 제27권6호
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  • Pages.881-885
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  • 2006
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Vibronic Emission Spectrum of Jet-Cooled o-Tolunitrile in a Corona Excited Supersonic Expansion

  • Park, Chan-Ho (Department of Chemistry and The Chemistry Institute for Functional Materials, Pusan National University) ;
  • Lee, Gi-Woo (Department of Chemistry and The Chemistry Institute for Functional Materials, Pusan National University) ;
  • Lee, Sang-Kuk (Department of Chemistry and The Chemistry Institute for Functional Materials, Pusan National University)
  • 발행 : 2006.06.20
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초록

We have employed a technique of corona excited supersonic expansion to generate electronically excited but jet-cooled o-tolunitrile. The vibronically well-resolved emission spectrum of the jet-cooled o-tolunitrile in the $S_{1}\rightarrow S_{0}$ transition was recorded in the uv region using a Fourier transform spectrometer equipped with a Quartz-uv beam splitter. The electronic transition and vibrational mode frequencies in the ground electronic state were accurately determined from the analysis of the spectra observed.

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참고문헌

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피인용 문헌

  1. Electronic spectra of 2- and 3-tolunitrile in the gas phase. II. Geometry changes from Franck-Condon fits of fluorescence emission spectra vol.144, pp.8, 2016, https://doi.org/10.1063/1.4941924
  2. Assignment of Vibronic Emission Spectra of Jet-Cooled m-Tolunitrile vol.27, pp.9, 2006, https://doi.org/10.5012/bkcs.2006.27.9.1377
  3. Reassignment of Isomeric Dimethylbenzyl Radicals Generated by Corona Discharge of 1,2,4-Trimethylbenzene vol.29, pp.12, 2006, https://doi.org/10.5012/bkcs.2008.29.12.2341
  4. Physical Chemistry Research Articles Published in the Bulletin of the Korean Chemical Society: 2003-2007 vol.29, pp.2, 2008, https://doi.org/10.5012/bkcs.2008.29.2.450
  5. Franck Condon spectra of the 2-tolunitrile dimer and the binary 2-tolunitrile water cluster in the gas phase vol.1143, pp.None, 2006, https://doi.org/10.1016/j.molstruc.2017.04.092