폴리이미드 종류에 따른 연성 동박 적층판의 부착력 연구

Research on the Adhesion of Flexible Copper Clad Laminates According to Species of Polyimide

  • 이재원 (한국기술교육대학교 신소재공학과) ;
  • 김상호 (한국기술교육대학교 신소재공학과)
  • Lee Jae Won (Dept. of Materials Engineering , Korea University of Technology and Education) ;
  • Kim Sang Ho (Dept. of Materials Engineering , Korea University of Technology and Education)
  • 발행 : 2005.04.01

초록

Flexible copper clad laminates (FCCL) fabricated by sputtering has advantages in fine pitch etching and dimensional accuracy than previous casting or laminating type FCCL, But its lower adhesion is inevitable technical challenge to solve for commercializing it. Chromium (Cr) which strongly reacts with O moiety was used as tie-coating layer in order to improve low adhesion between copper (Cu) and polyimide (PI). Sputtering raw polyimide (SRPI) and casting raw polyimide (CRPI) were used as substrates at this research. PI was pretreated by plasma before sputtering, and each sample was varied with RF power and Cr thickness on sputtering. Peel strength of the FCCL on SRPI was higher than that on CRPI. Adhesion had maximum value when 10 nm of Cr was deposited on SRPI by RF power of 50 W. It seems to be by the formation of Cu-Cr-O solid solution at the metal-PI interface.

키워드

참고문헌

  1. 'Weekly Electronics Information', Electronics Information, 7(4) (2004) 1
  2. F. Barlow, A. Lostetter, A. Elshabini, Microelectronics Reliability, 42(7) (2002) 1091 https://doi.org/10.1016/S0026-2714(02)00061-6
  3. S. S. Jo, Y. H. Kim, Journal of the MicroElectronics & Packaging Society, 10(2) (2003) 39
  4. E. Kondoh, Thin Solid Films, 359(2) (2000) 255 https://doi.org/10.1016/S0040-6090(99)00872-X
  5. H. G., Kim, B. J. Lee, J. T. Kim, Y. B. Kim,. D. C. Lee, Journal of the Korean Institute of Electrical and Electronic Material Engineers, 11(5) (1998) 340
  6. S. J. Park, K. S. Cho, S. H. Kim, HWAHAK KONGHAK, 40(5) (2002) 613
  7. I. Satoru, M. Takehiro, F. Shin, N. Shouhei, S. Kazufuyu, F. Nobuhiro, Vaccum, 51(4) (1998) 615 https://doi.org/10.1016/S0042-207X(98)00260-7
  8. 'IPC-TM-650 Test Methods Manual', the Institute for Interconnecting and Packaging Electronic Circuits 2215 Sanders Road Northbook, IL 60062-6135
  9. E. A. Brandes, G. B. Rrook, 'Smithells Metals Reference Book', Seventh Edition. (1992)
  10. S. W. Russell, S. A. Rafalski, R. L. Spreitzer, J. Li, M. Moinpour, F. Moghadam, T. L. Alford, Thin Solid Films, 262 (1995) 154 https://doi.org/10.1016/0040-6090(94)05812-1