Fabrication of Precise Patterns using a Laser Beam Expanding Technique in Nano-Replication Printing (nRP) Process

레이저 빔 단면확대를 이용한 나노 복화(複畵)공정의 패턴 정밀도 향상에 관한 연구

  • 박상후 (한국과학기술원 기계공학과 대학원) ;
  • 임태우 (한국과학기술원 기계공학과 대학원) ;
  • 양동열 (한국과학기술원 기계공학과) ;
  • 이신욱 (한국과학기술원 물리학과 대학원) ;
  • 공홍진 (한국과학기술원 물리학과)
  • Published : 2005.01.01

Abstract

A laser beam expanding technique is employed to fabricate precise nano-patterns in a nano-replication printing (nRP) process. In the nRP process, some patterns can be fabricated in the range of several microns inside on a polymerizable resin by using a volume-pixel (voxel) matrix that is transformed from a two-tone bitmap figure file. The liquid monomers are polymerized by means of a two-photon-absorption (TPA) phenomenon that is induced by a femtosecond (fs)-pulse laser. The yokels are generated consecutively to merge into adjoining yokels in the process of fabricating a pattern. The resolution of a fabricated pattern can be obtained under the diffraction limit of a laser beam by the two-photon absorbed polymerization (TPP). In this work, a beam-expanding technique has been applied to enlarge a working area and to fabricate precise patterns. Through this work, a working area is expanded by the technique as much as 2.5 times compared with a case of without a beam expanding technique, and precision of outside patterns is improved.

Keywords

References

  1. Chou, S.Y., Keimel, C; Gu, J., 'Ultrafast and direct imprint ofnanostructures in silicon,' Nature, Vol.417, No.20, pp.835-837, 2002
  2. Xia, Y., Whitesides, G.M., 'Soft lithography,' Angew. Chem. Int. Ed., Vol.37, pp.550-575, 1998
  3. Loo, Y.L., Lang, D.V., Rogers, J.A., Hsu, J.W.P., 'Electrical contacts to molecular layers by nanotransfer printing,' Nano Letters, Vol. 3, No.7, pp.913-917,2003 https://doi.org/10.1021/nl034207c
  4. Aizenberg, J., Black, A. J., Whitesides, G. M., 'Control of crystal nucleation by patterned selfassembled monolayers,' Nature, Vol. 398, No.8, pp.495- 198, 1999
  5. Schaper, C.D., 'Patterned transfer of metallic thin film nanostructures by water-soluble polymer templates,' Nano Letters, Vol.3, No.9, pp.1305-1309, 2003 https://doi.org/10.1021/nl034412s
  6. Schmid, H., Michel, B., 'Siloxane polymers for high- resolution, high-accuracy soft lithography, Macromolecules, Vol. 33, pp.3042-3049, 2000 https://doi.org/10.1021/ma982034l
  7. Kim, C. S., Shtein, M., Forrest, S. R., 'Nanolithography based on patterned metal transfer and its application to organic electronic devices,' Appl. Phy. Letters., Vol. 80, No. 21, pp.4051-4053, 2002 https://doi.org/10.1063/1.1481980
  8. Kim, C. S., Burrows, P. E., Forrest, S. R., 'Micropatterning of organic electronic devices by cold-welding,' Science, Vol. 288, pp.831-833, 2000 https://doi.org/10.1126/science.288.5467.831
  9. Kim, Y.S., Suh, K.Y., Lee, H.H., 'Fabrication of three-dimensional microstructures by soft molding,' Applied Physics Letters, Vol.79, No.14, pp.2285-2287,2001 https://doi.org/10.1063/1.1407859
  10. Hong, S.H., Zhu, J, Mirkin, CA, 'Multiple ink nanolithography: toward a multiple-pen nanoplotter,' Science, Vol. 286, pp.523-525, 1999 https://doi.org/10.1126/science.286.5439.523
  11. Sun, H.B., Maeda, M., Takada, K., Chon, J.W.M., Gu, M., Kawata, S., 'Experimental investigation of single voxels for laser nanofabrication via twophoton photopolymerization,' Applied Physics Letters, Vol. 83, No.5, pp.819-821, 2003 https://doi.org/10.1063/1.1598293
  12. Kawata, S., Sun, H.B., Tanaka, T., Takada, K., 'Finer features for functional microdevices,' Nature, Vol. 412, No. 16, pp. 697-698,2001 https://doi.org/10.1038/35089130
  13. Serbin, J., Egbert, A., Ostendorf, A., Chichkov, B.N., 'Femtosecond laser-induced two-photon polymerization of inorganic-organic hybrid materials for applications in photonics,' Optics letters, Vol. 28, No.5, pp.301-303, 2003 https://doi.org/10.1364/OL.28.000301
  14. Maruo, S., Kawata, S., 'Two-photon-absorbed nearinfrared photopolymerization for three-dimensional microfabrication,' J. of Microelectromechanical Systems, Vol. 7, No.4, pp.411-415, 1998 https://doi.org/10.1109/84.735349
  15. Sun, H. B., Tanaka, T., Kawata, S., 'Threedimensional focal spots related to two-photon excitation,' Applied Physics Letters, Vol. 80, No. 20, pp.3673-3675, 2002 https://doi.org/10.1063/1.1478128
  16. Park, S.H., Lim, T.W., Yang, D.Y., Yi, S.w., Kong, H.J., 'Development of a nano replication printing (nRP) process using a voxel matrix scanning scheme,' J. of KSPE, Vol. 21, No.2, pp.210-217, 2004
  17. Park, S.H., Lim, T.W, Yang, D.Y., Kong, H,J., 'Directly nano-precision feature patterning on thin metal layer using top-down building approach in nRP process,' J. of KSPE, Vol.21, No.6, pp.153-159, 2004
  18. Lim, T.W., Park, S.H., Yang, D.Y., Yi, S.W., Kong, H.J., 'Development of contour offset algorithm in nRP process for fabricating nano-precision features,' J. ofKSPE, Vol. 21, No.6, pp.160-166, 2004
  19. Park, S.H., Lim, T.W, Yang, D.Y., Kong, H.J., 'Fabrication of a PDMS (poly-dimethylsiloxane) stamp using nano-replication printing process,' J. of KSME, Vol.28, No.7, pp.999-1005, 2004 https://doi.org/10.3795/KSME-A.2004.28.7.999
  20. Sun, H.B., Matsuo, S., Misawa, H., 'Three dimensional photonic crystal structures achieved with two-photon-absorption photopolymerization of resin,' Applied. Phys. Letters, Vol. 74, No.6, pp.786-788, 1999 https://doi.org/10.1063/1.123367
  21. Cronin, P. J., Torok, P., Varga, P., Cogswell, C., 'High-aperture diffraction of a scalar off-axis Gaussian beam,' J. Opt. Soc. Am. -A, Vol. 17, No.9, pp.1556-1564, 2000 https://doi.org/10.1364/JOSAA.17.001556