Effect of $N_2$-backflushing Time in Carbon Ceramic UF & MF System for Paper Wastewater Treatment

  • Park, Jin-Yong (Department of Environmental Sciences & Biotechnology, Hallym University)
  • 발행 : 2005.12.01

초록

The wastewater discharged from a paper plant was filtrated by 3 kinds of tubular carbon ceramic UF and MF membranes with $N_2$-backflushing. The filtration time (FT) was fixed at 8 min or 16 min, and $N_2$-backflushing time (BT) was changed in 0${\~}$60 sec. The optimal condition was discussed in the viewpoints of total permeate volume ($V_T$), dimensionless permeate flux (J/Jo) and resistance of membrane fouling ($R_f$). In the viewpoints of $V_T$, J/Jo and $R_f$, the optimal $N_2$-BT was 40 sec at both FT for M9 (MWCO: 300,000 Daltons) and C005 ($0.05{\mu}m$) membranes. However, for C010 ($0.1{\mu}m$) it was 10 sec at FT=8 min, and 20 sec at FT=16 min in the viewpoints of J/Jo and $R_f$, and 5 sec at both FT in the viewpoints of $V_T$. It means that the short $N_2$-BT could reduce the membrane fouling and recover the permeate flux sufficiently for MF membrane having a large pore size as C010. Average rejection rates of pollutants were higher than $99.0\%$ for turbidity and $22.8{\~}59.6\%$ for $COD_{cr}$, but rejection rates of total dissolved solid (TDS) were lower than $8.9\%$. Therefore, the low turbidity water purified in our system could be reused for paper process.

키워드

참고문헌

  1. G. Tchobanoglous, J. Darby, K Bourgeous, J. McArdle, P. Genest, and M. Tylla, 'Ultrafiltration as an advanced tertiary treatment process for municipal wastewater', Desalination, 119, 315 - 322 (1998) https://doi.org/10.1016/S0011-9164(98)00175-1
  2. M. Cheryan and N. Rajagopalan, 'Membrane processing of oily streams wastewater treatment and waste reduction', J. Membrane Sci., 151, 13 - 28 (1998) https://doi.org/10.1016/S0376-7388(98)00190-2
  3. J. H. Roorda and J. H. J. M. van der Graaf, 'Understanding membrane fouling in ultrafiltration of WWTP-effluent', Water Sci. and Tech., 41 (10-11), 345 - 353 (2000)
  4. S. L. Li, K. S. Chou, J. Y. Lin, H. W. Yen, and I. M. Chu, 'Study on the microfiltration of Escherichia coli-containing fermentation broth by a ceramic membrane filter', J. Membrane Sci., 110, 203-210 (1996) https://doi.org/10.1016/0376-7388(95)00250-2
  5. F. F. Nazzal and M. R. Wiesner, 'pH and ionic strength effects on the performance of ceramic membranes in water filtration', J. Membrane Sci., 93, 91-103 (1994) https://doi.org/10.1016/0376-7388(94)85019-4
  6. J. Y. Park, C. K. Choi, and J. J. Kim, 'A Study on dynamic separation of silica slurry using a rotating membrane filter: 1. experiments and filtrate fluxes' , J. Membrane Sci., 97, 263 - 273 (1994) https://doi.org/10.1016/0376-7388(94)00167-W
  7. C. K. Choi, J. Y. Park, W. C. Park, and J. J. Kim, 'A Study on dynamic separation of silica slurry using a rotating membrane filter: 2. modeling of cake formation', J. Membrane Sci., 157, 177 -187 (1999) https://doi.org/10.1016/S0376-7388(98)00377-9
  8. R. H. Davis, S. Redkar, and V. T. Kuberkar, 'Modeling of concentration and depolarization with high-frequency backpulsing', J. Membrane Sci., 121, 229-242 (1996) https://doi.org/10.1016/S0376-7388(96)00179-2
  9. P. Srijaroonrat, E. Julien, and Y. Aurelle, 'Unstable secondary oil/water emulsion treatment using ultrafiltration', J. of Membrane Sci., 159, 11-20 (1999) https://doi.org/10.1016/S0376-7388(99)00044-7
  10. R. Sondhi, Y. S. Lin, and F. Alvarez, 'Crossflow filtration of chromium hydroxide suspension by ceramic membrane: fouling and minimization by backpulsing', J Membrane Sci., 174, 111-122 (2000) https://doi.org/10.1016/S0376-7388(00)00384-7
  11. V. T. Kuberkar and R. H. Davis, 'Microfiltration of protein-cell mixtures with crossflushing or backflushing', J. Membrane Sci., 183, 1-14 (2001) https://doi.org/10.1016/S0376-7388(00)00577-9
  12. M. Heran and S. Elmaleh, 'Microfiltration through an inorganic tubular membrane with high frequency retrofiltraton', J. Membrane Sci., 188, 181 -188 (2001) https://doi.org/10.1016/S0376-7388(01)00351-9
  13. M. H. Kim and J. Y. Park, 'Membrane fouling control effect of periodic water-back-flushing in the tubular carbon ceramic ultrafiltration system for recycling paper wastewater', Membrane J, 11 (4), 190-203 (2001)
  14. H. J. Hwang and J. Y. Park, 'Effect of periodic $N_2$-back-flushing in paper wastewater treatment using carbon ceramic ultrafiltration and microfiltration membranes', Membrane J., 12(1), 8-20 (2002)
  15. H. Carrene, F. Blaszkow, and H. R. Balmann, 'Modelling the clarification of lactic acid fermentation broths by cross-flow microfiltration', J Membrane Sci., 186, 219-230 (2001) https://doi.org/10.1016/S0376-7388(00)00677-3