Bulletin of the Korean Chemical Society

  • 제26권2호
  • /
  • Pages.253-259
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  • 2005
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Crystal Packing of Two Different Tetranuclear Iron(III) Clusters, [(tacn)4Fe4O2(OH)4]2.8Br.9H2O (tacn = 1,4,7-triazacyclononane)

  • Jin, Mi-Kyung (Department of Chemistry-BK21 and the Institute of Basic Sciences, Sungkyunkwan University) ;
  • Kim, Yoo-Jin (Department of Chemistry-BK21 and the Institute of Basic Sciences, Sungkyunkwan University) ;
  • Jung, Duk-Young (Department of Chemistry-BK21 and the Institute of Basic Sciences, Sungkyunkwan University) ;
  • Heu, Min (Department of Physics, The Catholic University of Korea) ;
  • Yoon, Seok-Won (Department of Physics, The Catholic University of Korea) ;
  • Suh, Byoung-Jin (Department of Physics, The Catholic University of Korea)
  • 발행 : 2005.02.20
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초록

[$(tacn)_4Fe_4O_2(OH)_4]_2{\cdot}8Br{\cdot}9H_2O$ (tacn = 1,4,7-triazacyclononane), a tetranuclear iron(III) complex was synthesized by the hydrolysis of (tacn)FeCl3 and crystallizes in the orthorhombic space group, Pca2(1), with cell parameters, a = 37.574(3) $\AA$, b = 16.9245(12) $\AA$, c = 14.2830(11) $\AA$, V = 9082.9(12) ${\AA}^3$. [$(tacn)_4Fe_4O_2(OH)_4]^{4+}$ cations approach S4 point symmetry containing an adamantane skeleton. Four Fe(III) atoms have distorted octahedral environments with two hydroxo and an oxo bridges. Two [$(tacn)_4Fe_4O_2(OH)_4]^{4+}$ clusters having different Fe…Fe distances are connected to each other by the networked hydrogen bonds. The electrochemical behavior reveals irreversible three cathodic and two anodic peaks. Magnetic properties are characterized by antiferromagnetic (AF) interactions between Fe(III) ion spins. However, the low-lying states are still magnetic and exhibit a blocking behavior and a magnetic hysteresis at low temperatures.

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