Bulletin of the Korean Chemical Society

  • 제26권11호
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  • Pages.1738-1742
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  • 2005
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Novel Triiodide PVC-Based Membrane Sensor Based on a Charge Transfer Complex of Iodine and Bis(2-hydroxyacetophenone)butane-2,3-dihydrazone

  • 발행 : 2005.11.20
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초록

In this study a novel triiodide ion-selective electrode based on a charge transfer complex of iodine and Bis(2-hydroxyacetophenone)butane-2,3-dihydrazone (ICT), as a membrane carrier was prepared. The electrode has a linear dynamic range between 1.0 ${\times}$ $10^{-2}$ and 5.0 ${\times}$ $10^{-7}$ M, with a Nernstian slope of 58. 99 ${\pm}$ 0.3 mV $decade^{-1}$ and detection limit of 3.0 ${\times}$ $10 ^{-7}$ M. The potentiometric response of the proposed sensor is independent of the pH of the solution in the pH range of 3.0-10.0. The electrode possesses the advantages of short conditioning time, fast response time, and especially, very good selectivity over a large number of common organic and inorganic anions. The electrode can be used for at least 6 months without any considerable divergences in the potentials. It was used as an indicator electrode in potentiometric titration of triiodide ion with thiosulfate.

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참고문헌

  1. Hofmeister, P. Arch. Exp. Pathol. Pharmacol. 1888, 24, 247 https://doi.org/10.1007/BF01918191
  2. Yuan, R.; Chai, Y. Q.; Liu, D.; Gao, D.; Li, J. Z.; Yu, R. Q. Anal. Chem. 1993, 65, 2572 https://doi.org/10.1021/ac00067a005
  3. Gao, D.; Li, J. Z.; Yu, R. Q.; Zheng, G. D. Anal. Chem. 1994, 66, 2245 https://doi.org/10.1021/ac00086a008
  4. Ying, M.; Yuan, R.; Zhang, X. M.; Song, Y. Q.; Li, Z. Q.; Shen, G. L.; Yu, R. Q. Analyst 1997, 122, 1143 https://doi.org/10.1039/a700544j
  5. Li, Z. Q.; Yuan, R.; Ying, M.; Song, Y. Q.; Shen, G. L.; Yu, R. Q. Anal. Lett. 1997, 30, 1455 https://doi.org/10.1080/00032719708001667
  6. Chaniotakis, N. A.; Jurkschat, K.; Ruhlemann, A. Anal. Chim. Acta 1993, 282, 345 https://doi.org/10.1016/0003-2670(93)80220-F
  7. Hisamoto, H.; Siswanta, D.; Nishihara, H.; Suzuki, K. Anal. Chim. Acta 1995, 304, 171 https://doi.org/10.1016/0003-2670(94)00614-R
  8. Badr, I. H. A.; Meyerhoff, M. K.; Hassan, S. S. M. Anal. Chem. 1995, 67, 2613 https://doi.org/10.1021/ac00111a019
  9. Rothmaier, M.; Schaller, U.; Morf, W. E.; Pretsch, E. Anal. Chim. Acta 1996, 327, 17 https://doi.org/10.1016/0003-2670(96)00055-4
  10. Jyo, A.; Minakami, R.; Kanda, Y.; Egawa, H. Sens. Actuators B 1993, 13, 200 https://doi.org/10.1016/0925-4005(93)85361-D
  11. Blair, T. L.; Allen, J. R.; Daunert, S.; Bachas, L. G. Anal. Chem. 1993, 65, 2155 https://doi.org/10.1021/ac00063a039
  12. Gao, D.; Gu, J.; Yu, R. Q.; Zheng, G. D. Analyst 1995, 120, 499 https://doi.org/10.1039/an9952000499
  13. Malinowska, E.; Meyerhoff, M. E. Anal. Chim. Acta 1995, 300, 33 https://doi.org/10.1016/0003-2670(94)00407-D
  14. Sun, C. Q.; Zhao, J. H.; Xu, H. D.; Sun, Y. P.; Zhang, X.; Shen, J. C. Talanta 1998, 46, 15 https://doi.org/10.1016/S0039-9140(97)00256-7
  15. Ganjali, M. R.; Pourjavid, M. R.; Poursaberi, T.; Rezapour, M.; Javanbakht, M.; Sharghi, H. Anal. Sci. 2003, 19, 995 https://doi.org/10.2116/analsci.19.995
  16. Ganjali, M. R.; Yousefi, M.; Poursaberi, T.; Naji, L.; Salavati- Niasari, M.; Shamsipur, M. Electroanalysis 2003, 15, 1476 https://doi.org/10.1002/elan.200302679
  17. Shamsipur, M.; Rouhani, S.; Mohajeri, A.; Ganjali, M. R.; Rashidi-Ranjbar, P. Anal. Chim. Acta 2000, 418, 197 https://doi.org/10.1016/S0003-2670(00)00954-5
  18. Ganjali, M. R.; Pourjavid, M. R.; Rezapour, M.; Poursaberi, A.; Salavati-Niasari, M. Anal. Lett. 2003, 36, 881 https://doi.org/10.1081/AL-120019250
  19. Poursaberi, T.; Hossieni, M.; Taghizadeh, M.; Pirelahi, H.; Shamsipur, M.; Ganjali, M. R. Microchem. J. 2002, 72, 77 https://doi.org/10.1016/S0026-265X(01)00159-X
  20. Ganjali, M. R.; Mizani, F.; Emami, M.; Salavati-Niasari, M.; Shamsipour, M.; Yousefi, M.; Javanbakht, M. Electroanaysis 2003, 15, 139 https://doi.org/10.1002/elan.200390015
  21. Ganjali, M. R.; Mizani, F.; Salavati-Niasari, M. Anal. Chim. Acta 2003, 481, 85 https://doi.org/10.1016/S0003-2670(03)00075-8
  22. Farhadi, K.; Maleki, R. Anal. Sci. 2002, 18, 133 https://doi.org/10.2116/analsci.18.133
  23. Farhadi, K.; Maleki, R.; Shamsipur, M. Electroanalysis 2002, 14, 760 https://doi.org/10.1002/1521-4109(200206)14:11<760::AID-ELAN760>3.0.CO;2-Q
  24. Suzuki, H.; Nakagawa, H.; Minfune, M.; Saito, Y. Anal. Sci. 1993, 9, 351 https://doi.org/10.2116/analsci.9.351
  25. Ganjali, M. R.; Shamsipur, M.; Emami, M.; Salavati-Niasari, M.; Javanbakht, M.; Yousefi, M. Sens. Actuators B 2005, 105, 127 https://doi.org/10.1016/S0925-4005(03)00625-7
  26. Farhadi, K.; Bonab, H. S.; Maleki, R.; Shamsipur, M.; Sharghi, H. J. Chin. Chem. Soc. 2002, 49, 861
  27. Rouhollahi, A.; Shamsipur, M. Anal. Chem. 1999, 71, 1350 https://doi.org/10.1021/ac981077x
  28. Sadeghi, S.; Dashti, G. R. Anal. Chem. 2002, 74, 2591 https://doi.org/10.1021/ac010647h
  29. Kamata, S.; Bhale, A.; Fukunaga, Y.; Murata, H. Anal. Chem. 1988, 60, 2464 https://doi.org/10.1021/ac00173a006
  30. Yang, X. H.; Kumar, N.; Chi, H.; Hibbert, D. B.; Alexander, P. W. Electroanalysis 1997, 9, 549 https://doi.org/10.1002/elan.1140090709
  31. Zare, H. R.; Ardakani, M. M.; Nasirizadeh, N.; Safari, J. Bull. Korean Chem. Soc. 2005, 26, 51 https://doi.org/10.5012/bkcs.2005.26.1.051
  32. Ganjali, M. R.; Matloobi, P.; Ghorbani, M.; Norouzi, P.; Salavati- Niasari, M. Bull. Korean Chem. Soc. 2005, 26, 38 https://doi.org/10.5012/bkcs.2005.26.1.038
  33. Ganjali, M. R.; Zamani, H. A.; Norouzi, P.; Adib, M.; Rezapour, M.; Aceedy, M. Bull. Korean Chem. Soc. 2005, 26, 57934
  34. Tavakkoli, N. Bull. Korean Chem. Soc. 2004, 25, 1474 https://doi.org/10.5012/bkcs.2004.25.10.1474
  35. Ganjali, M. R.; Ghorbani, M.; Daftari, A.; Norouzi, P.; Pirelahi, H.; Dargahani, H. D. Bull. Korean Chem. Soc. 2004, 25, 172 https://doi.org/10.5012/bkcs.2004.25.2.172
  36. Ganjali, M. R.; Babaei, L. H.; Taghvaei-Ganjali, S.; Modjallal, A.; Shamsipur, M.; Hosseini, M.; Javanbakht, M. Bull. Korean Chem. Soc. 2004, 25, 77
  37. Ganjali, M. R.; Pourjavid, M. R.; Mouradzadegun, K.; Hosseini, M.; Mizani, F. Bull. Korean Chem. Soc. 2003, 24, 1585 https://doi.org/10.5012/bkcs.2003.24.11.1585
  38. Ganjali, M. R.; Daftari, A.; Mizani, F.; Salavati-Niasari, M. Bull. Korean Chem. Soc. 2003, 24, 23 https://doi.org/10.5012/bkcs.2003.24.1.023
  39. Ganjali, M. R.; Emami, M.; Salavati-Niasari, M. Bull. Korean Chem. Soc. 2002, 23, 1394 https://doi.org/10.5012/bkcs.2002.23.10.1394
  40. Schaller, U.; Bakker, E.; Spichiger, U. E.; Pretsch, E. Anal. Chem. 1994, 66, 391 https://doi.org/10.1021/ac00075a013
  41. Ammann, D.; Pretsch, E.; Simon, W.; Lindner, A.; Bezegh, A.; Pungor, E. Anal. Chim. Acta 1985, 171, 119 https://doi.org/10.1016/S0003-2670(00)84189-6
  42. Eugster, R.; Spichiger, U. E.; Simon, W. Anal. Chem. 1993, 65, 689 https://doi.org/10.1021/ac00054a007
  43. IUPAC Analytical Chemistry Revision, Commission on Analytical Nomenclature Recommendations for Nomenclature of Ion Selective Electrodes. Pure Appl. Chem. 1976, 48, 127 https://doi.org/10.1351/pac197648010127
  44. Christian, G. D. Analytical Chemistry; Wiley & Sons: New York, 1986 (ISBN: 0-471-21472-8)
  45. Umezawa, Y.; Umezawa, K.; Sato, H. Pure Appl. Chem. 1995, 67, 507 https://doi.org/10.1351/pac199567030507
  46. Rouhollahi, A.; Kakanejadifard, A.; Farnia, S. M. F.; Shamsipur, M. Polish J. Chem. 1997, 71, 731
  47. Myers, O. E. J. Chem. Phys. 1958, 28, 1027 https://doi.org/10.1063/1.1744338

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