Bulletin of the Korean Chemical Society

  • 제26권11호
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  • Pages.1743-1748
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  • 2005
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Dehydrogenation of Ethylbenzene with Carbon Dioxide as Soft Oxidant over Supported Vanadium-Antimony Oxide Catalyst

  • Hong, Do-Young (Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Vislovskiy, Vladislav P. (Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Park, Sang-Eon (Department of Chemistry, Inha University) ;
  • Park, Min-Seok (Department of Biotechnology & Food Science, Mongolia International University) ;
  • Yoo, Jin-S. (Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Chang, Jong-San (Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT))
  • 발행 : 2005.11.20
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초록

This work presents that carbon dioxide, which is a main contributor to the global warming effect, could be utilized as a selective oxidant in the oxidative dehydrogenation of ethylbenzene. The dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst has been studied under different atmospheres such as inert nitrogen, steam, oxygen or carbon dioxide as diluent or oxidant. Among them, the addition of carbon dioxide gave the highest styrene yield (up to 82%) and styrene selectivity (up to 97%) along with stable activity. Carbon dioxide could play a beneficial role of a selective oxidant in the improvement of the catalytic behavior through the oxidative pathway.

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  1. Activity studies of vanadium, iron, carbon and mixed oxides based catalysts for the oxidative dehydrogenation of ethylbenzene to styrene: a review vol.5, pp.12, 2015, https://doi.org/10.1039/C5CY00996K
  2. A new perspective on catalytic dehydrogenation of ethylbenzene: the influence of side-reactions on catalytic performance vol.5, pp.7, 2015, https://doi.org/10.1039/C5CY00457H
  3. vol.41, pp.10, 2017, https://doi.org/10.1039/C7NJ01022B
  4. Ethylbenzene Dehydrogenation with CO2 over V2O5-Fe2O3/Al2O3-TiO2 Catalyst vol.550-553, pp.1662-8985, 2012, https://doi.org/10.4028/www.scientific.net/AMR.550-553.301
  5. An Overview on the Dehydrogenation of Alkylbenzenes with Carbon Dioxide over Supported Vanadium–Antimony Oxide Catalysts vol.11, pp.1-2, 2007, https://doi.org/10.1007/s10563-007-9021-5
  6. Dehydrogenation of Ethylbenzene to Styrene with Carbon Dioxide Over ZrO2-based Composite Oxide Catalysts vol.12, pp.1, 2008, https://doi.org/10.1007/s10563-007-9039-8
  7. Unique influence of rare earth (Pr, Nd, and Er) oxide surface acidic texture over CeO2/γ-Al2O3 catalysts for selective production of styrene using CO2 flow pp.1568-5675, 2019, https://doi.org/10.1007/s11164-019-03761-z
  8. Dehydrogenation of Ethylbenzene with Carbon Dioxide over Supported Vanadium- Antimony Oxide Catalysts: Effect of Zirconia Modification in Alumina Support vol.27, pp.5, 2005, https://doi.org/10.5012/bkcs.2006.27.5.789
  9. Selective conversion of ethylbenzene into styrene over K2O/TiO2-ZrO2 catalysts: Unified effects of K2O and CO2 vol.269, pp.1, 2005, https://doi.org/10.1016/j.molcata.2006.12.021
  10. Advantage of Co Embedded γ-Al2O3 Catalysts Over MgO and SiO2 Solid Oxides in the Selective Production of Styrene Monomer vol.149, pp.11, 2019, https://doi.org/10.1007/s10562-019-02903-7
  11. Preferential adsorption of CO2 on cobalt ferrite sites and its role in oxidative dehydrogenation of ethylbenzene vol.38, pp.3, 2005, https://doi.org/10.1007/s43153-021-00121-6