Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Headspace Hanging Drop Liquid Phase Microextraction and GC-MS for the Determination of Linalool from Evening Primrose Flowers

  • Kim, Nam-Sun (Department of Chemistry, Seoul Women's University) ;
  • Jung, Mi-Jin (Department of Chemistry, Seoul Women's University) ;
  • Yoo, Zoo-Won (Department of Chemistry, Seoul Women's University) ;
  • Lee, Sun-Neo (Department of Chemistry, Seoul Women's University) ;
  • Lee, Dong-Sun (Department of Chemistry, Seoul Women's University)
  • Published : 2005.12.20
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Abstract

Headspace hanging drop liquid phase micro-extraction (HS-HD-LPME) is studied as a novel solvent-based sample pretreatment method for floral volatile aroma compounds. This paper reports on application of the HSHD- LPME combined with GC-MS for the analysis of linalool component emitted from evening primrose flowers. The effect of several variables on the method performance was investigated. Additionally, the separation of enantiomers on a cyclodextrin capillary column was performed to identify chirality of (−)-linalool component. Since the unsurpassed volume of a few micro-liters of solvent is used, there is minimal waste or exposure to toxic organic solvents. This method enables to combine extraction, enrichment, clean-up, and sample introduction into a single step prior to the chromatographic process.

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References

  1. Steffen, A.; Pawliszyn, J. J. Agric. Food Chem. 1996, 44, 2187 https://doi.org/10.1021/jf950727k
  2. Marriott, P. J.; Shellie, R.; Cornwell, C. J. Chromatogr. A 2001, 936, 1 https://doi.org/10.1016/S0021-9673(01)01314-0
  3. Bicchi, C.; Drigo, S.; Rubiolo, P. J. Chromatogr. A 2000, 892, 469 https://doi.org/10.1016/S0021-9673(00)00231-4
  4. Miller, M. E.; Stuart, J. D. Anal. Chem. 1999, 71, 23 https://doi.org/10.1021/ac980576v
  5. Kim, N. S.; Lee, D. S. J. Sep. Sci. 2004, 27, 96 https://doi.org/10.1002/jssc.200301603
  6. Lee, S. N.; Kim, N. S.; Lee, D. S. Anal. Bioanal. Chem. 2003, 377, 749 https://doi.org/10.1007/s00216-003-2163-z
  7. Kim, N. S.; Lee, D. S. J. Chromatogr. A 2002, 982, 31 https://doi.org/10.1016/S0021-9673(02)01445-0
  8. Yoo, Z. W.; Kim, N. S.; Lee, D. S. Bull. Korean Chem. Soc. 2004, 25, 271 https://doi.org/10.5012/bkcs.2004.25.2.271
  9. Liu, H.; Dasgupta, P. K. Anal. Chem. 1996, 68, 1817 https://doi.org/10.1021/ac960145h
  10. Liu, H.; Dasgupta, P. K. Tr. Anal. Chem. 1996, 15, 468
  11. Liu, S.; Dasgupta, P. K. Anal. Chem. 1995, 67, 2042 https://doi.org/10.1021/ac00109a023
  12. Jeannot, M. A.; Cantwell, F. F. Anal. Chem. 1996, 68, 2236 https://doi.org/10.1021/ac960042z
  13. He, Y.; Lee, H. K. Anal. Chem. 1997, 69, 4634 https://doi.org/10.1021/ac970242q
  14. Psillakis, E.; Kalogerakis, N. J. Chromatogr. A 2001, 907, 211 https://doi.org/10.1016/S0021-9673(00)01017-7
  15. Psillakis, E.; Kalogerakis, N. Trends Anal. Chem. 2002, 21, 53
  16. de Jager, L. S.; Andrews, A. R. J. Chromatographia 1999, 50, 733 https://doi.org/10.1007/BF02497313
  17. Theis, A. L.; Waldack, A. J.; Hansen, S. M.; Jeannot, M. A. Anal. Chem. 2001, 73, 5651 https://doi.org/10.1021/ac015569c
  18. Przyjazny, A.; Kokosa, J. M. J. Chromatogr. A 2002, 977, 143 https://doi.org/10.1016/S0021-9673(02)01422-X
  19. Yamini, Y.; Hojjati, M.; Haji-Hosseini, M.; Shamsipur, M. Talanta 2004, 62, 265 https://doi.org/10.1016/j.talanta.2003.07.012
  20. Zhao, R. S.; Lao, X. J.; Xu, X. B. Talanta 2004, 62, 751 https://doi.org/10.1016/j.talanta.2003.09.035
  21. Psillakis, E.; Kalogerakis, N. J. Chromatogr. A 2001, 938, 113 https://doi.org/10.1016/S0021-9673(01)01417-0
  22. Hou, L.; Lee, H. K. J. Chromatogr. A 2002, 976, 377 https://doi.org/10.1016/S0021-9673(02)01152-4
  23. Zabaras, D.; Wyllie, S. G. Flavour Fragr. J. 2001, 16, 411 https://doi.org/10.1002/ffj.1025
  24. Zhang, Z.; Pawliszyn, J. Anal. Chem. 1993, 65, 1843 https://doi.org/10.1021/ac00062a008
  25. Brenna, E.; Fuganti, C.; Serra, S. Tetrahedron: Asymmetry 2003, 14, 1 https://doi.org/10.1016/S0957-4166(02)00713-9
  26. Bicchi, C.; D'Amato, A.; Rubiolo, P. J. Chromator. A 1999, 843, 99 https://doi.org/10.1016/S0021-9673(99)00202-2

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