Study on the Characteristics of Dielectric Barrier Discharging System and Usability as a Disinfectant

2계면 플라즈마 방전시스템(DBD System)의 특징 및 소독제로서 방전수의 사용가능성에 대한 연구

  • 류승민 (한국과학기술원 건설 및 환경공학과) ;
  • 박희경 (한국과학기술원 건설 및 환경공학과) ;
  • 이봉주 (한국기초과학지원연구원)
  • Received : 2004.07.16
  • Accepted : 2004.07.30
  • Published : 2004.08.15

Abstract

Innovated technique to inactivate microorganisms has been developed. This technique uses plasma discharge in 2-phase (Air-Water). Dielectric Barrier (two phase) Discharging system is able to produce new oxidants for microorganisms. Products from discharging are $HNO_2$, $NO_2{^-}$, $HNO_3$, $NO_3{^-}$ and ozone but many other radicals can be generated as well. DBD water has low concentration of ozone (about 0.5mg/L), $NO_2{^-}$, $NO_3{^-}$ (about 10mg-N/L, 20mg-N/L respectively) and lots of $H^+$. These products play an important role in oxidation. Oxidation power by KI titration methods is approximately equivalent to $50mg-O_3/L$. Surprisingly stored DBD water could oxidize KI and maintain stable pH (about pH3) even after several days. Stored DBD water for 5 days has also more than 4log disinfection power to E. coli. However, DBD water cannot be used for drinking water directly due to it's toxicity. Additional process to neutralize pH and decrease toxicity must be applied.

Keywords

References

  1. 박노석, 주대성, 박회경 (1998) 배$\cdot$급수 관망내에서 상수 오염에 관한 연구. 대한환경공학희지, 20 , pp. 1095-1101
  2. 오현제 , 왕창근, 강준원 동 (2001) 오존/AOP 및 활성탄 조합 정수공정의 최적화 및 자동제어시스탱 개발, G- 7 프로젝트, 환경부
  3. 장재연 (2002) 수돗물에 대한 신뢰도. 서울시 수질평가위원회 심포지엄
  4. 환경부 (2002) 상수도 통계
  5. Alexandre Samouilov, Periannan Kuppusamy, Jay L. Zweier (1998) Evaluation of the Magnitude and Rate of Nitric Oxide Production from Nitrite in Biological Systems, Archives Of Biochemistry and Biophysics, 357, pp. 1-7
  6. Bruno Langlais, David A. Reckhow, Deborah R. Brink (1991) Ozone in Water Treatment, Lewis Publishers, Washington, D.C.
  7. Idil Arslan Alaton, lsil Akmehmet Balcioglu, Detlef W. Bahnemann (2002) Advanced oxidation of a reactive dyebath effluent: Comparison of $O_{3}$, $H_{2}O_{2}$/UV-C and TiO2/UV-A processes, Water Research, 36, pp. 1143-1154
  8. J. Pinart et, al. (1996) Quantitative study of the formation of inorganic chemical species following corona discharge-I. Production of $HNO_{2}$ and $HNO_{3}$ in a compositioncontrolled, humid atmosphere, Atmospheric environment, 30, pp. 129-132
  9. Lenore S. Clescerl et. al. (1998) Standard methods. 20th edition. APHA, Washington, D.C.
  10. Matthew J. Moorcroft, James Davis, Richard G. Compton (2001) Detection and determination of nitrate and nitrite: a review, Talanta, 54, pp. 785-803
  11. Pei Xu, Marie-Laure Janexb et, al. (2002) Wastewater disinfection by ozone: main parameters for process design, Water Research, 36, pp. 1043-1055
  12. Robert M. Clark, Mano Sivagenesan, Eugene W. Rice, Jimmy Chen (2002) Development of a Ct equation for the inactivation of Cryptosporidium oocysts with ozone, Water Research, 36(12), pp. 3141-3149 https://doi.org/10.1016/S0043-1354(02)00006-4
  13. V. Camel, A. Bermond (1998) The use of ozone and associated oxidation processes in drinking water treatment, Water Research, 32, pp. 3208-3222
  14. Yuko Kitamaki, Ji-Ye Jin, Toyohide Takeuchi (2003) Determination of inorganic anions via postcolumn reaction with iodide in ion chromatography, Journal of Pharmaceutical and Biomedical Analysis, 30, pp. 1751-1757