한국결정학회지 (Korean Journal of Crystallography)

한국결정학회 (Korean Crystallographic Association)
권호 표지

4중 가교 산소 리간드를 함유한 1차원 아연 배위 고분자:$[Zn_4(1,3- BDC)_3({\mu}_4-O)\; (pyridine)_2]$ (1,3-BDC : 1, 3-benzenedicarboxylate)

1-Dimensional Zinc Polymer Containing the Quadruply Bridging Oxygen Ligand : $[Zn_4(1,3- BDC)_3({\mu}_4-O)\;(pyridine)_2]$

  • Min Dongwon (Department of Chemistry(BK21), Sungkyunkwan University) ;
  • Lee Soon W. (Department of Chemistry(BK21), Sungkyunkwan University)
  • 발행 : 2004.12.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

피리딘 존재 하에서 zinc(II) nitrate $(Zn(NO_3)_2{\cdot}6H_2O)$와 $1,3-BDCH_2\;(1,3-BDC=1,3-benzenedicarboxylate)$의 수열, 용매 반응으로 1차원 배위 고분자 $[Zn_4(1,3- BDC)_3({\mu}_4-O)\; (pyridine)_2]$ (1)이 얻어졌다. X-ray구조 결정 결과,고분자 1이 4중 가교 산소 리간드를 갖고 있음이 밝혀졌다. 고분자 1는 2개의 띠로 구성되어 있으며, 각 띠는 1,3-BDC 리간드에 의해서 단위체들이 연결되어 된다.

The hydro(solve)thermal reaction of zinc(II) nitrate $(Zn(NO_3)_2{\cdot}6H_2O)$ with $1,3-BDCH_2\;(1,3-BDC= 1,3-benzenedicarboxylate)$ in the presence of pyridine a gave 1-dimensional zinc polymer $[Zn(1,3- BDC)({\mu}_4-O)\;(pyridine)_2]$ (1). X-ray structure determination revealed that polymer 1 has a quadruply bridging oxygen $({\mu}_4-O)$ ligand. This polymer consists of two strands linked by 1,3-BDC ligands, and each strand is formed by connecting the monomer units by 1,3-DBC ligands.

키워드

참고문헌

  1. Kesanli, B. and Lin, W., Coord. Chem. Rev., 246, 305 (2003)
  2. Swiergers, G.F. and Malefetse, T.J., Coord. Chem. Rev., 225, 91 (2002)
  3. Eddaoudi, M., Kim, J., Rosi, N., Vodak, D., Wachter, J., O'Keeffe, M., and Yaghi, O.M., Science, 295, 469 (2002)
  4. Moulton, B. and Zaworotko, M.J., Chem. Rev., 101, 1629 (2001)
  5. Zaworotko, M.J., Chem. Commun., 1 (2001)
  6. Swiergers, G.F. and Malefetse, T.J., Chem. Rev., 100, 3483 (2000)
  7. Janiak, C., Angew. Chem., Int. Ed. Engl., 36, 1431 (1997)
  8. Munakata, M., Wu, L.P. and Kuroda-Sowa, T., Adv. Inorg. Chem., 46, 173 (1999)
  9. Chui, S.S.-Y., Lo, S.M.-F., Charmant, J.P.H., Orpen, A.G. and Williams, I.D., Science, 283, 1148 (1999)
  10. Kiang, Y.-H., Gardner, G.B., Lee, S., Xu, Z. and Lobkovsky, E.B., J. Am. Chem. Soc., 121, 8204 (1999)
  11. Min, D., Yoon, S.S., Lee, C.Y., Suh, M., Hwang, Y.-J., Han, W.S. and Lee, S.W., Bull. Korean Chem. Soc., 22, 531 (2001)
  12. Min, D., Yoon, S.S., Lee, J.H., Suh, M. and Lee, S.W., Inorg. Chem. Commun., 4, 297 (2001)
  13. Min, D., Yoon, S.S., Lee, C.Y., Han, W.S. and Lee, S.W., Bull. Korean Chem. Soc., 22, 1041 (2001)
  14. Min, D., Yoon, S.S., Jung, D.Y., Lee, C.Y., Kim, Y., Han, W.S. and Lee, S.W., Inorg. Chim. Acta, 324, 293 (2001)
  15. Kim, H.J., Min, D., Hoe, H.S. and Lee, S.W., J. Korean Chem. Soc., 45, 507 (2001)
  16. Min, D., Yoon, S.S. and Lee, S.W., Inorg. Chem. Commun., 5, 143 (2002)
  17. Huh, H.S., Min, D., Lee, Y.K. and Lee, S.W., Bull. Korean Chem. Soc., 23, 619 (2002)
  18. Min, D. and Lee, S.W., Inorg. Chem. Commun., 5, 978 (2002)
  19. Min, D. and Lee, S.W., Bull. Korean Chem. Soc., 23, 948 (2002)
  20. Baeg, J.Y. and Lee, S.W., Inorg. Chem. Commun., 6, 313 (2003)
  21. Lee, Y.K. and Lee, S.W., Bull. Korean Chem. Soc., 24, 906 (2003)
  22. Lee, S.W., Kim, H.J., Lee, Y.K., Park, K., Son, J.-H. and Kwon, Y.-U., Inorg. Chim. Acta, 353, 151 (2003)
  23. Baeg, J.Y., Kim, H.N., Lee, Y.K. and Lee, S.W., Korean J. Cryst., 15, 5 (2004)
  24. Bruker, SHELXTL, Structure Determination Software Programs, Bruker Analytical X-ray Instruments Inc., Madison, Wisconsin, USA, 1997
  25. Mehrotra, R.C. and Bohra, R., Metal Carboxylates Academic Press: New York, 1983
  26. Gordon, A.J. and Ford, R.A., The Chemist's Companion: A Handbook of Practical Data, Techniques, and References Wiley: New York, 1972