폐비닐 열분해 재활용품 중의 잔류농약 분석

Determination of Residual Pesticides in Recycle Product of Waste Plastic Pyrolysis

  • 신혜순 (덕성여자대학교 약학대학) ;
  • 심성훈 (한국기계연구원 환경기계기술연구부)
  • 발행 : 2004.09.01

초록

Environmental waste treatment technology is transforming from incineration system to pyrolysis gasification system. And there it is necessary for our country to adapt gasification system urgently to prevent the land pollution and lack of landfill area. The objective of this study was to determine the pesticides residues of derived product of pyrolysis gasification system for recycling of waste plastic by gas chromatograph-mass selective detector and nitrogen phosphorus detector. The residual pesticides were not detected in derived product of waste recyling. But some pesticide was detected on raw level (0.02 ~ 0.05 ppm) in waste plastic sample.

키워드

참고문헌

  1. Ambrus A. Application of multiresdue procedures in pesti-cides residues analysis, Pure & Appl. Chem., 1986; 58(7): 1035-1062 https://doi.org/10.1351/pac198658071035
  2. Bicchi C, D'amato AC and Lee SM. Multiresidue method for quantitative gas chromatographic determination of pesticide residues in sweet cherries. JournaI of AOAC intemational., 1997; 80(6): 1281-1287
  3. Cho H, Hwang I and Choi B. Determination of residual pesticides in crude drugs-gas chromatographic Analysis of 18 pesticides- Kor. J Pharmacogn. 2001; 32(3): 200-211
  4. Feuerriegel U, Kunsch M, Stahlberg R and Steiger F. The matehal and energy balance of the thermoselect process: The thermoselect process for the degasification and gasification of wastes. Schweitzer, F.J. (Ed). Efverlag. 1994; 69-84
  5. Garcia-Repetto R, Garrido I and Repetto M. Determination of organochlorine, organophorus, and trizine pesticide residues in wine by gas chlromatography with electron capture and nitrogen-phosphorus detection. Journal of AOAC international. 1996; 79(6): 1423-1439
  6. Hemingway RJ. Improved cost effective approaches to pesticide residues analysis. Pure and Appl. Chem. 1984; 56: 1132-1138
  7. Holland PT. Mass spectometric determination of pesticide residues. Pure and Appl. Chem. 1990; 62: 317-322 https://doi.org/10.1351/pac199062020317
  8. Lee C, Park K and Shin H. A Study on Organochlorine and Organophosphorus Pesticide Residues of Korean Commercial Teas. J. Fd Hyg. Safety 1996; 11(2): 99-105
  9. Luke M A, Froberg JE, Doose GM and Masumoto HT. Improved miltiresidue gas chromatographic determi-nation of organophosphorus, organonitrogen conduc-tivity detectors, J. Assoc. Off. Anal. Chem., 1985; 64(5): 1187-1185
  10. Oehme M, St$\ddot o$ckl D and Kn$\ddot o$ppel H. Comparison of the reproducibility of negative ion chemical ionization mass spectra obtained by different reagent gases on two commercial quadrupole instruments. Anal. Chem. 1986; 58:554-558 https://doi.org/10.1021/ac00294a013
  11. Omura M, Hashimoto K, Ohta K, Iio T, Ueda S, Ando K and Hiraide H. Relative retention time diagram as a useful tool for gas chromatographic analysis and electron capture detection of pestisides. J. Assoc. Off. Anal. Chem. 1990; 73(2): 300-306
  12. Pho K, Kim H and Lee Y. Simultaneous determination of various pesticides: Analysis utilizing GC/MSD (SIM mode). Korean J. Food. Sci. Technol. 1998; 30(4): 721-727
  13. S Mark Lee, Michael L Papathakis, Hsiao-Ming C Feng, Gray F Hunter and Joyce E Carr. Multipesticide residue method for fruit and vegetables, Fresenius J. Anal. Chem., 1991;339: 376-383 https://doi.org/10.1007/BF00322352
  14. Stahlberg R and Feuerriegel U. Thermoselect-energy and raw materials recovery, Part 1: process foundation for the continuous utilization of waste. Chem. Technik, 1994; 46: 257-266
  15. Tomoko Itoyama. Simple and rapid systemic determination of various pesticides in brown rice by gas chromatog-raphy, 1995; 36(4): 516-524
  16. Wolf HP. Possible new therapeutic approach in diabetes mellitus by inhibition of carnitine palmitoyltransferase 1 (CPT1). Horm. Metab. Res. Suppl. 1992; 26: 62-67