전기도금법에 의해 생성된 Ni-B 합금도금층의 물성에 미치는 B 함량의 영향

Influence of B Content on Properties of Ni-B Electrodeposit

  • 이규환 (한국기계연구원 표면연구부) ;
  • 장도일 (한국기계연구원 표면연구부) ;
  • 권식철 (한국기계연구원 표면연구부)
  • 발행 : 2004.08.01

초록

The influence of the boron content on the various properties of Ni-B alloy films produced by electrodeposition was investigated. The considerable reduction in grain size was observed with increasing boron content. The internal stress was tensile and increased linearly with increasing boron content. Hardness increased up to $750H_{v}$ at 2 at% boron and then kept the value to 11 at% boron for as-plated Ni-B coatings. The hardness of Ni-B films increased up to $1,250H_{v}$ due to the intermetallic$ Ni_3$B precipitation by the heat treatment, and maximum hardness of each coating increases with boron content. Wear resistance decreased with increasing the boron content because of high friction coefficient and brittle fracture of film which has higher content of boron.

키워드

참고문헌

  1. M. Donten, J. Osteryoung, J. Appl. Electrochem., 21 (1992) 496 https://doi.org/10.1007/BF01018601
  2. O. Younes, E. Gileadi, T. Electrochem. Soc., 149 (2002) C100 https://doi.org/10.1149/1.1433750
  3. V. D. Papachristos, C. N. Panagopoulos, P. Leisner, M. B. Olsen, U. Wahlstrom, Surf. Coat. Techol, 105 (1998) 224 https://doi.org/10.1016/S0257-8972(98)00459-9
  4. H. D. Park, D. Chang, K. H. Lee, S. G. Kang, Plating & Surface Finishing, 88 (2001) 64
  5. T. V. Gaevskaya, I. G. Novotortseva, L. S. Tsybulskaya, Metal Finishing, (1996) 100
  6. M. Onoda, L. Shimizu, Y. Tateishi, T. Watanabe, Trans. IMF, 76 (1), (1998) 41 https://doi.org/10.1080/00202967.1998.11871191
  7. T. Yamasaki, Scripta Matehalia, 44 (2001) 1497 https://doi.org/10.1016/S1359-6462(01)00720-5
  8. G. Graef, K. Anderson, J. Groza, A. Palazoglu, Mater. Sci. Eng., B41 (1996) 253
  9. D. H. Jeong, U. Erb. K. T. Aust, G. Palumbo, Scripta Materialia, 48 (2003) 1067