Study on the Thermal Properties and High Impact of Elastic Epoxy Blend System

탄성에폭시 블렌드 시스템의 열적 특성 및 내충격성에 관한 연구

  • 이경용 (원광대 전기전자및정보공학부) ;
  • 이관우 (원광대 전기전자및정보공학부) ;
  • 민지영 (원광대 전기전자및정보공학부) ;
  • 최용성 (원광대 전기전자및정보공학부) ;
  • 박대희 (원광대 전기전자및정보공학부)
  • Published : 2004.04.01

Abstract

Elastic-factor of elastic epoxy were investigated by TMA (Thermomechanical Analysis), DMTA (Dynamic Mechanical Thermal Analysis), TGA (Thermogravimetric Analysis) and FESEM (Field Emission Scanning Electron Microscope) for structure-images analysis as toughness-investigation to improve brittleness of existing epoxy resin. A range of measurement temperature of the TMA and DMTA was changed from -20($^{\circ}C$) to $200^{\circ}(C)$, and TGA was changed from $0^{\circ}(C)$ to $600^{\circ}(C)$. Glass transition temperature (Tg) of elastic epoxy was measured through thermal analysis devices with the content of 0(phr), 20(phr) and 35(phr). Also, thermal expansion coefficient (a), high temperature, modulus and loss factor were investigated through TMA, TGA, and DMTA. In addition, the structure of specimens was analyzed through FESEM, and then elastic-factor of elastic epoxy was visually showed by FESEM. As thermal analysis results, 20(phr) was more excellent than 30(phr) thermally and mechanically. Specially, thermal expansion coefficient, high temperature, modulus, and damping properties were excellent. By structure-images analysis through FESEM, we found elastic-factor of elastic epoxy that is not existing epoxy, and proved high impact.

Keywords

References

  1. 김성철, 고분자공학I, 희중당, 1994, Chapter 1-14
  2. 윤태성, '고강도 에폭시/폴리썰폰 블렌드의 경화 거동(I): 등온 DSC 열분석', Polymer(Korea), Vol. 20, No. 3, pp. 403-411, 1996
  3. 윤홍수, '아미노포스파젠 유도체에 의한 에폭시 수지의 경화와 열적성질', Journal of the Korean Society of Dyers and Finishers, Vol. 11, N. 6, pp. 7-17, 1996
  4. 정광섭, '에폭시 수지 시스템의 기계 및 열적 특성에 관한 연구', 한국 복합 재료학회 논문지 (복합재료), Vol. 10, No. 4, pp. 1-10, 1997
  5. 박수진, 'Bisphenol계 DGEBA/DGEBS 에폭시 블렌드 시스템의 열적 특성 및 파괴인성', Polymer(Korea), Vol. 27, No. 1, pp. 33-39, 2003
  6. 조수형, '에폭시 수지계 중성자 차폐재 제조 및 특성', 한국재료학회 논문지, Vol. 8, No. 5, pp. 457-463 1998
  7. 송영욱, 김상욱, 'TGA 분석에 의한 DGEBA/MDA/PGE계의 열분해 특성', 서울시립대학교 산업기술연구소 논문집, Vol. 6, No. 1, pp. 117-120, 1998
  8. 서울시립대학교 산업기술연구소 논문집 v.6 no.1 TGA 분석에 의한 DGEBA/MDA/PGE계의 열분해 특성 송영욱;김상욱