Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Characterization of Highly Crystalline Anatase Nanowire Arrays

  • Zhao, Yong-Nan (Department of Materials Science, School of Materials Science and Chemical Engineering, Tianjin Polytechnic University) ;
  • Lee, U-Hwang (Department of Chemistry and BK21 School of Molecular Science, Sungkyunkwan University) ;
  • Suh, Myung-Koo (Department of Chemistry and BK21 School of Molecular Science, Sungkyunkwan University) ;
  • Kwon, Young-Uk (Department of Chemistry and BK21 School of Molecular Science, Sungkyunkwan University)
  • Published : 2004.09.20
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Abstract

We developed a novel synthesis strategy of titania nanowire arrays by employing simple hydrothermal reaction and ion-exchange reaction techniques. Hydrothermal reactions of metallic titanium powder with $H_2O_2$ in a 10 M NaOH solution produced a new sodium titanate compound, $Na_2Ti_6O_{13}{\cdot}xH_2O$ (x~4.2), as arrays of nanowires of lengths up to 1 mm. Acid-treatment followed by calcination of this material produced arrays of highly crystalline anatase nanowires as evidenced by x-ray diffraction, Raman spectroscopy, and transmission electron microscopy studies. In both cases of sodium titanate and anatase, the nanowires have exceptionally large aspect ratios of 10,000 or higher, and they form arrays over a large area of $1.5 {\times} 3 cm^2$. Observations on the reaction products with varied conditions indicate that the array formation requires simultaneously controlled formation and crystal growth rates of the $Na_2Ti_6O_{13}{\cdot}xH_2O$ phase.

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References

  1. Patzke, G. R.; Krumeich, F.; Nesper, R. Angew. Chem. Inter. Ed.2002, 35, 2446.
  2. Hu, J.; Odom, T. W.; Lieber, C. M. Acc. Chem. Res. 1999, 32,435. https://doi.org/10.1021/ar9700365
  3. Kovtyukhova, N. I.; Mallouk, T. E. Chem. Eur. J. 2002, 8, 4355.
  4. Xia, Y.; Yang, P.; Sun, Y.; Wu, Y.; Mayers, B.; Gates, B.; Yin, Y.;Kin, F.; Yan, H. Adv. Mater. 2003, 15, 353. https://doi.org/10.1002/adma.200390087
  5. Lao, J. Y.; Huang, J. Y.; Wang, D. Z.; Ren, Z. F. Adv. Mater. 2004,16, 65. https://doi.org/10.1002/adma.200305684
  6. Lew, K. K.; Pan, L.; Dickey, E. C.; Redwing, J. M. Adv. Mater.2003, 15, 2073. https://doi.org/10.1002/adma.200306035
  7. Zhou, J.; Xu, N. S.; Deng, S. Z.; Chen, J.; She, J. C. Chem. Phys.Lett. 2003, 382, 443. https://doi.org/10.1016/j.cplett.2003.10.002
  8. Jung, W. S. Bull. Korean Chem. Soc. 2004, 25, 51. https://doi.org/10.5012/bkcs.2004.25.1.051
  9. Prieto, A. L.; Martin-Gonzalez, M.; Kenyani, J.; Grosky, R.;Sands, T.; Stacy, A. M. J. Am. Chem. Soc. 2003, 125, 2388. https://doi.org/10.1021/ja029394f
  10. Sander, M. S.; Prieto, A. M.; Gronsky, R.; Sands, T.; Stacy, A. M.Adv. Mater. 2002, 14, 665. https://doi.org/10.1002/1521-4095(20020503)14:9<665::AID-ADMA665>3.0.CO;2-B
  11. Zhang, Y.; Li, G.; Wang, Y.; Zhang, B.; Song, W.; Zhang, L. Adv.Mater. 2002, 14, 1227. https://doi.org/10.1002/1521-4095(20020903)14:17<1227::AID-ADMA1227>3.0.CO;2-2
  12. Schonenberger, C.; van der Zander, B. M. I.; Fokkink, L. G. J.;Henny, M.; Schmid, C.; Kruger, M.; Bachtold, A.; Huber, R.;Staufer, U. J. Phys. Chem. B 1997, 101, 5497. https://doi.org/10.1021/jp963938g
  13. Yang, H.; Shi, Q.; Tian, B.; Lu, Q.; Gao, F.; Xie, S.; Fan, J.; Yu, C.;Tu, B.; Zhao, D. J. Am. Chem. Soc. 2003, 125, 4724. https://doi.org/10.1021/ja034005i
  14. Jin, C. G.; Xiang, X. Q.; Jia, C.; Liu, W. F.; Cai, W. L.; Yao, L. Z.;Li, X. G. J. Phys. Chem. B 2004, 108, 1844. https://doi.org/10.1021/jp036133z
  15. Tian, Y. T.; Meng, G. W.; Gao, T.; Sun, S. H.; Xie, T.; Peng, X. S.;Ye, C. H.; Zhang, L. D. Nanotechnology 2004, 15, 189. https://doi.org/10.1088/0957-4484/15/1/036
  16. Wang, Y. C.; Leu, I. C.; Hon, M. H. J. Appl. Phys. 2004, 95,1444. https://doi.org/10.1063/1.1637710
  17. Zhang, H. M.; Guo, Y. G.; Wan, L. J.; Bai, C. L. Chem. Commun.2003, 3022.
  18. Yoon, C. H.; Suh, J. S. Bull. Korean Chem. Soc. 2002, 23, 1519. https://doi.org/10.5012/bkcs.2002.23.11.1519
  19. Park, I. S.; Jang, S. R.; Hong, J. S.; Vittal, R.; Kim, K. J. Chem.Mater. 2003, 15, 4633. https://doi.org/10.1021/cm030541y
  20. Huang, L.; Wang, H.; Wang, Z.; Mitra, A.; Zhao, D.; Yan, Y.Chem. Mater. 2002, 14, 876. https://doi.org/10.1021/cm010819r
  21. Huang, L.; Wang, H.; Wang, Z.; Mitra, A.; Bozhilov, K. N.; Yan,Y. Adv. Mater. 2002, 14, 61. https://doi.org/10.1002/1521-4095(20020104)14:1<61::AID-ADMA61>3.0.CO;2-Y
  22. Greene, L. E.; Law, M.; Goldberger, J.; Kim, F.; Johnson, J. C.;Zhang, Y.; Saykally, R. J.; Yang, P. Angew. Chem. Int. Ed. Engl.2003, 42, 3031. https://doi.org/10.1002/anie.200351461
  23. Rao, C. N. R.; Deepak, F. L.; Gundiah, G.; Govindara, A. Prog.Solid State Chem. 2003, 31, 5. https://doi.org/10.1016/j.progsolidstchem.2003.08.001
  24. Wang, W.; Li, Y. J. Am. Chem. Soc. 2002, 124, 2880. https://doi.org/10.1021/ja0177105
  25. Xu, A.; Fang, Y.; You, L.; Liu, H. J. Am. Chem. Soc. 2003, 125,1494. https://doi.org/10.1021/ja029181q
  26. Liu, B.; Zeng, H. C. J. Am. Chem. Soc. 2003, 125, 4430. https://doi.org/10.1021/ja0299452
  27. Li, Y.; Wang, J.; Deng, Z.; Wu, Y.; Sun, X.; Yu, D.; Yang, P. J. Am.Chem. Soc. 2001, 123, 9904. https://doi.org/10.1021/ja016435j
  28. Cao, M.; Hu, C.; Peng, G.; Qi, Y.; Wang, E. J. Am. Chem. Soc.2003, 125, 4982. https://doi.org/10.1021/ja029620l
  29. Wang, X.; Li, Y. Angew. Chem. Int. Ed. 2002, 41, 4790. https://doi.org/10.1002/anie.200290049
  30. Li, Y.; Ding, Y.; Wang, Z. Adv. Mater. 1999, 11, 847. https://doi.org/10.1002/(SICI)1521-4095(199907)11:10<847::AID-ADMA847>3.0.CO;2-B
  31. Sun, X.; Chen, X.; Li, Y. Inorg. Chem. 2002, 41, 4996. https://doi.org/10.1021/ic0257827
  32. Tian, Z. R.; Voigt, J. A.; Liu, J.; McKenzie, B.; McDermott, M. J.;Rodriguez, M. A.; Konish, K.; Xu, H. Nat. Mater. 2003, 2, 821. https://doi.org/10.1038/nmat1014
  33. Zhang, Y. X.; Li, G. H.; Jin, Y. X.; Zhang, Y.; Zhang, J.; Zhang, L.D. Chem. Phys. Lett. 2002, 365, 300. https://doi.org/10.1016/S0009-2614(02)01499-9
  34. Du, G. H.; Chen, Q.; Che, R. C.; Yuan, Z. Y.; Peng, L. M. Appl.Phys. Lett. 2001, 79, 3702. https://doi.org/10.1063/1.1423403
  35. Chen, Q.; Zhou, W.; Du, G.; Peng, L. Adv. Mater. 2002, 14, 1208. https://doi.org/10.1002/1521-4095(20020903)14:17<1208::AID-ADMA1208>3.0.CO;2-0
  36. Miao, Z.; Xu, D.; Ouyang, J.; Guo, G.; Zhao, X.; Tang, Y. NanoLett. 2002, 2, 717. https://doi.org/10.1021/nl025541w
  37. Lei, Y.; Zhang, L. D.; Meng, G. W.; Li, G. H.; Zhang, X. Y.;Liang, C. H.; Chen, W.; Wang, S. X. Appl. Phys. Lett. 2001, 78,1125. https://doi.org/10.1063/1.1350959
  38. Hoyer, P. Langmuir 1996, 12, 1411. https://doi.org/10.1021/la9507803
  39. Zhang, X. Y.; Zhang, L. D.; Chen, W.; Meng, G. W.; Zheng, M. J.;Zhao, L. X. Chem. Mater. 2001, 13, 2511. https://doi.org/10.1021/cm0007297
  40. Kasuga, T.; Hiramatsu, M.; Hoson, A.; Sekino, T.; Niihara, K.Langmuir 1998, 14, 3160. https://doi.org/10.1021/la9713816
  41. Limmer, S. J.; Cao, G. Adv. Mater. 2003, 15, 427. https://doi.org/10.1002/adma.200390099
  42. Li, D.; Xia, Y. Nano Lett. 2003, 3, 555. https://doi.org/10.1021/nl034039o
  43. Feist, T. P.; Davies, P. K. J. Solid State Chem. 1992, 101, 275. https://doi.org/10.1016/0022-4596(92)90184-W
  44. Anderson, S.; Wadsley, A. D. Acta Crystallogr. 1961, 14, 1245. https://doi.org/10.1107/S0365110X61003636
  45. Zhang, W. F.; He, Y. L.; Zhang, M. S.; Yin, Z.; Chen, Q. J. Phys.D: Appl. Phys. 2000, 33, 912. https://doi.org/10.1088/0022-3727/33/8/305
  46. Choi, H. C.; Jung, Y. M.; Kim, S. B. Bull. Korean Chem. Soc.2004, 25, 426. https://doi.org/10.1007/s11814-008-0072-8
  47. Bersani, D.; Lottici, P. P.; Ding, X. Z. Appl. Phys. Lett. 1998, 72,73. https://doi.org/10.1063/1.120648
  48. Lagarec, K.; Desgreniers, S. Solid State Commun. 1995, 94, 519. https://doi.org/10.1016/0038-1098(95)00129-8
  49. Parker, J. C.; Siegel, R. W. Appl. Phys. Lett. 1990, 57, 943. https://doi.org/10.1063/1.104274

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