Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Visual Detection of Di-and Tri-phosphates in Aqueous Solution of Neutral pH

  • Han, Min-Su (Center for Integrated Molecular Systems and Department of Chemistry, Divisioin of Molecular and Life Sciences, Pohang University of Science and Technology) ;
  • Kim, Dong H. (Center for Integrated Molecular Systems and Department of Chemistry, Divisioin of Molecular and Life Sciences, Pohang University of Science and Technology)
  • Published : 2004.08.20
Download PDF
⟨ Previous Next ⟩

Abstract

The chemosenssor that consists of [$Zn_2$(1,3-bis[bis(2-pyridylmethyl)aminomethyl]benzene)]$^{4+}$ (receptor) and pyrecatechol violet (signaling unit) detects with naked eyes di- and tri-phosphates conjugated to nucleosides or in free forms. The blue color of the aqueous solution (pH 7.0) of the sensor turns to yellow upon exposing to the analytes.

Keywords

References

  1. Beer, P.D.;Schmitt, P. Curr. Biol. Chem. Biol. 1997, 1, 475 https://doi.org/10.1016/S1367-5931(97)80041-5
  2. Beer, P.D.;Gale, P.A. Angew. Chem. Int. Ed. 2001, 40, 486. https://doi.org/10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.0.CO;2-P
  3. Masrtinez-Manez, R;Sancenon, F. Chem. Rev. 2003, 103, 4419. https://doi.org/10.1021/cr010421e
  4. Aoki, S.; Kimura, E. Rev. Mol. Biotech.2002, 90, 129. https://doi.org/10.1016/S1389-0352(01)00070-8
  5. Fabbrizzi, L.; Leone, A.; Taglietti, A. Angew. Chem. Int. Ed. 2001, 40, 3066. https://doi.org/10.1002/1521-3773(20010817)40:16<3066::AID-ANIE3066>3.0.CO;2-0
  6. Fabbfizzi, L.; Marcotte, N.; Stomeo, F.; Taglietti, A. Angew. Chem. Int. Ed. 2002, 41, 3811. https://doi.org/10.1002/1521-3773(20021018)41:20<3811::AID-ANIE3811>3.0.CO;2-W
  7. Amendola, V.; Fabbrizzi, L.; Mangano, C.; Pallavicini, P.; Poggi, A.; Taglietti, A. Coord. Chem. Rev. 2001, 219-221, 821. https://doi.org/10.1016/S0010-8545(01)00368-X
  8. Cha, K.W.; Huang, H.Z.; Choi, H.C. Bull. Korean Chem. Soc. 2002, 23, 1456. https://doi.org/10.5012/bkcs.2002.23.10.1456
  9. Han, M.S.; Kim, D.H. Angew. Chem. Int. Ed. 2002, 41, 3809. https://doi.org/10.1002/1521-3773(20021018)41:20<3809::AID-ANIE3809>3.0.CO;2-N
  10. Han, M.S.; Kim, D.H. Bioorg. Med. Chem. Lett. 2003, 13, 1079. https://doi.org/10.1016/S0960-894X(03)00055-6
  11. Kim, D.H.; Han, M.S. Bioorg. Med. Chem. Lett. 2003, 13, 2543. https://doi.org/10.1016/S0960-894X(03)00468-2
  12. Wiskur, S.L.; Ait-Haddou, H.; Lavigne, J.J.; Anslyn, E.V. Acc. Chem. Res. 2001, 34, 963. https://doi.org/10.1021/ar9600796
  13. Ait-Haddou, H.; Wiskur, S.L.; Lynch, V.M.; Anslyn, E.V. J. Am. Chem. Soc. 2001, 123, 11296. https://doi.org/10.1021/ja011905v
  14. Wiskur, S.L.; Anslyn, E.V. J. Am. Chem. Soc. 2001, 123, 10109. https://doi.org/10.1021/ja011800s
  15. Metzger, A.; Anslyn, E.V. Angew. Chem. Int. Ed. 1998, 37, 649. https://doi.org/10.1002/(SICI)1521-3773(19980316)37:5<649::AID-ANIE649>3.0.CO;2-H
  16. Niikura, K.; Metzger, A.; Anslyn, E.V. J. Am. Chem. Soc. 1998, 120, 8533. https://doi.org/10.1021/ja980990c
  17. Harris, D.C. Quantitative Chemical analysis, 4th ed.; Freeman and Co.: New York, 1995; p.352
  18. Kawahara, S.; Uchimaru, T. Eur. J. Inorg.Chem. 2001, 2437.
  19. Jelesarov, I.; Bosshard, H.R. J. Mol. Recog. 1999, 12, 3. https://doi.org/10.1002/(SICI)1099-1352(199901/02)12:1<3::AID-JMR441>3.0.CO;2-6
  20. Conners, K.A. Binding Constants, The Measurement of Molecular Complex Stability; John Wiley and Sons: New York, 1987;pp 24-28.
  21. Kuzmic, P.; Moss, M.L.; Kofron, J.L.; Rich, D.H. Anal. Biochem. 1992, 205, 65. https://doi.org/10.1016/0003-2697(92)90579-V
  22. Ochiai, E.J. Chem. Edu. 1988, 65, 943. https://doi.org/10.1021/ed065p943
  23. Bock, C. W.; Katz, A. K.; Glusker, J. P. J. Am. Chem. Soc. 1995, 117, 3754. https://doi.org/10.1021/ja00118a012
  24. Dudev, T.; Lim, C. J. Am. Chem. Soc. 2000, 122, 11146. https://doi.org/10.1021/ja0010296

Cited by

  1. Tuning colourimetric indicator displacement assays for naked-eye sensing of pyrophosphate in aqueous media vol.4, pp.4, 2013, https://doi.org/10.1039/c3sc22233k
  2. A highly sensitive gold nanoparticle-based colorimetric probe for pyrophosphate using a competition assay approach vol.49, pp.2, 2013, https://doi.org/10.1039/C2CC37379C
  3. Bis[zinc(ii)dipicolylamino]-functionalised peptides as high affinity receptors for pyrophosphate ions in water vol.49, pp.42, 2013, https://doi.org/10.1039/c3cc40937f
  4. The selectivity of water-based pyrophosphate recognition is tuned by metal substitution in dimetallic receptors vol.44, pp.26, 2015, https://doi.org/10.1039/C5DT00729A
  5. Metal complexation chemistry used for phosphate and nucleotide determination: an investigation of the Yb3+–pyrocatechol violet sensor vol.13, pp.8, 2008, https://doi.org/10.1007/s00775-008-0415-2
  6. Reversible Coordinative Bonds in Molecular Recognition vol.106, pp.9, 2004, https://doi.org/10.1021/cr010206y
  7. Metal-containing Trifurcate Chemosensing Ensemble for Phytate vol.19, pp.4, 2004, https://doi.org/10.1080/10610270701355034
  8. Complexation of bisphosphonates with ytterbium(III): Application of phosphate and ATP detection assay based on Yb3+–pyrocatechol violet vol.103, pp.12, 2004, https://doi.org/10.1016/j.jinorgbio.2009.09.006
  9. Selective sensing of ATP by hydroxide-bridged dizinc(II) complexes offering a hydrogen bonding cavity vol.48, pp.39, 2004, https://doi.org/10.1039/c9dt02404b