Bulletin of the Korean Chemical Society

  • 제25권1호
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  • Pages.106-108
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  • 2004
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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NMR Studies on the Isomerization of Vanadium(V)-Propylenediaminetetraacetate Complex in Solution

  • Han, Sang-Gyu (Department of Industrial Chemistry, Kyungpook National University) ;
  • Park, Sam-Soo (Department of Industrial Chemistry, Kyungpook National University) ;
  • Lee, Man-Ho (Department of Industrial Chemistry, Kyungpook National University) ;
  • Park, Heai-Ku (Department of Chemical System Engineering, Keimyung University)
  • 발행 : 2004.01.20
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초록

In this paper we have determined the thermodynamic parameters for the isomerization between the ${\alpha}$-cis and the ${\beta}$-cis isomers in vanadium(V)-propylenediaminetetraacetate complex in water by $^{51}V$ NMR spectroscopy. In addition, the effects of organic solvents (methanol, formamide and dimethylsulfoxide) and inorganic salts (NaCl, $NaClO_4\;and\;NH_4Cl$) on the isomerization in solution have been investigated.

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참고문헌

  1. Robson, R. L.; Eady, R. R.; Richardson, T. H.; Miller, R. W.;Hawkins, M.; Postgate, J. R. Nature 1986, 322, 388. https://doi.org/10.1038/322388a0
  2. Viller, H. Phytochemistry 1984, 23, 1387. https://doi.org/10.1016/S0031-9422(00)80471-9
  3. Smith, M. J.; Kim, D.; Horenstein, B.; Nakanishi, K.; Kustin, K.Acc. Chem. Res. 1991, 24, 117. https://doi.org/10.1021/ar00004a005
  4. Reder, D. Angew. Chem. Intl. Ed. Engl. 1991, 30, 148. https://doi.org/10.1002/anie.199101481
  5. Shechter, J.; Karlish, S. J. D. Nature 1980, 284, 556. https://doi.org/10.1038/284556a0
  6. Mcneill, J. H.; Yuen, V. G.; Hoveyda, H. R.; Orvig, C. J. Med.Chem. 1992, 35, 1489. https://doi.org/10.1021/jm00086a020
  7. Przyborowski, L; Schwarzenbach, G.; Zimmerman, T. Helv.Chim. Acta 1965, 48, 1556. https://doi.org/10.1002/hlca.19650480716
  8. Scheidt, W. R.; Countryman, R.; Hoard, J. L. J. Am. Chem. Soc.1971, 93, 3878. https://doi.org/10.1021/ja00745a008
  9. Scheidt, W. R.; Tsai, C. C.; Hoard, J. L. J. Am. Chem. Soc. 1971,93, 3867. https://doi.org/10.1021/ja00745a006
  10. Amos, L. W.; Sawyer, D. T. Inorg. Chem. 1972, 11, 2692. https://doi.org/10.1021/ic50117a024
  11. Kustin, K.; Toppen, D. L. J. Am. Chem. Soc. 1973, 95, 3564. https://doi.org/10.1021/ja00792a017
  12. Saito, K.; Sasaki, Y. Pure Appl. Chem. 1988, 60, 1123. https://doi.org/10.1351/pac198860081123
  13. Crans, D. C.; Shin, P. K. J. Am. Chem. Soc. 1994, 116, 1305. https://doi.org/10.1021/ja00083a016
  14. Crans, D. C.; Keramidas, A. D.; Mahroof-Tahir, M.; Anderson, O.P.; Miller, M. M. Inorg. Chem. 1996, 35, 3599. https://doi.org/10.1021/ic951270z
  15. Lee, M.-H.; Heo, N. H.; Oh, Y. K. Bull. Korean Chem. Soc. 2002,23, 1661. https://doi.org/10.5012/bkcs.2002.23.11.1661
  16. Yamada, S.; Nagase, J.; Funabashi, S.; Tanaka, M. J. Inorg. Nucl.Chem. 1976, 38, 617. https://doi.org/10.1016/0022-1902(76)80324-7
  17. Gutmann, V. Coord. Chem. Rev. 1976, 18, 225. https://doi.org/10.1016/S0010-8545(00)82045-7

피인용 문헌

  1. Ti-Catalyzed Selective Isomerization of Terminal Mono-substituted Olefins vol.26, pp.3, 2004, https://doi.org/10.5012/bkcs.2005.26.3.461