Bulletin of the Korean Chemical Society

  • 제25권10호
  • /
  • Pages.1471-1473
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  • 2004
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Lipase/Ruthenium-Catalyzed Dynamic Kinetic Resolution of β-Hydroxyalkylferrocene Derivatives

  • Lee, Han-Ki (National Research Laboratory of Chirotechnology, Department of Chemistry, Division of Molecular and Life Sciences, Pohang University of Science and Technology) ;
  • Ahn, Yang-Soo (National Research Laboratory of Chirotechnology, Department of Chemistry, Division of Molecular and Life Sciences, Pohang University of Science and Technology)
  • 발행 : 2004.10.20
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초록

An efficient dynamic kinetic resolution of racemic ${\beta}$-hydroxyalkylferrocene and 1,1'-bis( ${\beta}$-hydroxyalkyl)-ferrocene derivatives was achieved using lipase/ruthenium-catalyzed transesterification in the presence of an acyl donor. The racemic ${\beta}$-hydroxyalkylferrocene derivatives were successfully transformed to the corresponding chiral acetates of high optical purities in high yields.

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피인용 문헌

  1. Lipase/Ruthenium-Catalyzed Dynamic Kinetic Resolution of ?-Hydroxyalkylferrocene Derivatives. vol.36, pp.13, 2005, https://doi.org/10.1002/chin.200513197
  2. Dynamic Kinetic Resolutions and Asymmetric Transformations by Enzyme-Metal Combo Catalysis vol.26, pp.4, 2004, https://doi.org/10.5012/bkcs.2005.26.4.515
  3. Chemo-enzymatic synthesis of new ferrocenyl-oxazolidinones and their application as chiral auxiliaries vol.19, pp.7, 2008, https://doi.org/10.1016/j.tetasy.2008.03.009