환경위생공학 (Journal of environmental and Sanitary engineering)

대한환경위생공학회 (Korean Society for Environmental Sanitary Engineers)
권호 표지

1-Aza-12-Crown-4를 이용한 금속 이온 흡착제 수지 합성

Resin Synthesis of Adsorbent Metal Ions using 1-Aza-12-Crown-4

  • 김준태 (광주보건대학 환경행정과) ;
  • 노기환 (광주보건대학 환경행정과)
  • Kim Joon-Tae (Dept. of Environmental Administration, Gwangju Health College) ;
  • Roh Gi-Hwan (Dept. of Environmental Administration, Gwangju Health College)
  • 발행 : 2004.09.01
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초록

Content of chlorine in s쇼rene-DVB copolymer was decreased as crosslink increased and it is because as crosslink increased $1\%,\;2\%,\;5\%\;and\;10\%$ DVB content increased and crosslink density increased and cavity was reduced. Functional group of resin almost disappeared as C-C1 peak around $700cm^{-1}$ was substituted with 1-aza-12-C-4 macrocyclic ligand and new peak of C-N around $1020cm^{-1}$ appeared, so it was confirmed that styrene-DVB copolymer and ligand were compounded. As crosslink increased in the analysis of element contents, it resulted in the reduction of nitrogen content and it is because as crosslink increased, it led to the reduction of chlorine content in the process of substitution reaction and it affected macrocyclic ligand substituted. Form of functional synthetic resin showed distortion of its particles as macrocyclic ligand was introduced to styrene-DVB copolymer and hydrogen of ligand caused substitution with chlorine element of styrene molecule.

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참고문헌

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