Photocatalytic Oxidation of Indoor Air Volatile Organic Compounds (VOCs) in pub Level

  • Jo, Wan-Kuen (Department of Environmental Engineering, Kyungpook National University) ;
  • Kim, Dong-Hyun (Department of Chemical Engineering, Kyungpook National University) ;
  • Ki, Jae-Chang (Department of Chemical Engineering, Kyungpook National University) ;
  • Huh, Jeung-Soo (Department of Material Sciences and Metallurgy, Kyungpook Notional University)
  • 발행 : 2003.12.01

초록

This study evaluated the technical feasibility of the application of titanium oxide (TiO$_2$) photocatalysis for the removal of VOCs in low ppb concentrations commonly associated with non -occupational indoor air quality issues. A series of experiments were conducted to evaluate four parameters (relative humidity (RH), hydraulic diameter (HD), photocatalytic oxidation (PCO) reactor material (RM), and inlet port size (IPS) of PCO reactor) for the PCO destruction efficiencies of the selected target VOCs. None of the target VOCs presented significant dependency on the RH, which is inconsistent with a few previous studies. However, it is noted that the three parameters (HD, RM and IPS) should be considered for better VOCs removal efficiencies for the application of TiO$_2$ photocatalytic technology for cleansing non -occupational indoor air. The PCO destruction of VOCs at concentrations associated with non-occupational indoor air quality issues can be up to nearly 100%. The amount of CO generated during PCO would be negligible in comparison to the indoor CO levels. These results can make the PCO reactor an important tool in the effort to improve non-occupational indoor air quality.

키워드

참고문헌

  1. Anderson, M.A., W.A. Zeltner, X. Fu, D.T. Tompkins, and D.T. Reindl (1996)Photocatalytic degradation of formaldehyde and other VOCs in indoor air. Center for Indoor Air Research Currents, December, 1, 4
  2. Baek, S.O., Y.S. Kim, and R. Perry (1997) Indoor air quality in homes, offices and restaurants in Korean urban areas-indoor/outdoor relationships. Atmos. Environ. 31, 529-544
  3. Blanco, J., P. Avila, A. Bahamonde, E. Alvarez, B. Sanchez, and M. Romero (1996) Photocatalytic destruction of toluene and xylene at gas phase on a titania based monolithic catalyst. Catal. Today 29, 437-442
  4. Chan, C.Y., L.Y. Chan, X.M. Wang, Y.M. Liu, S.C. Lee, S.C. Zou, G.Y. Sheng, and J.M. Fu (2002) Volatile organic compounds in roadside microenvironments of metropolitan Hong Kong. Atmos. Environ., 36, 2039-2047
  5. Cho, I.C., J.H. Byun, E.S. Byun, D.G. Lee, and S.W. Kim (2001) Gas phase photocatalytic oxidation of PCE with $TiO_2$. J. Kor. Soc. Atmos. Environ., 17, 57-66
  6. Damme, H. and W.K. Hall (1981) Photocatalytic properties of Perovskites for $H_2$ and CO oxidation-influence of ferroelectric properties. J. Catal., 69, 371-383
  7. d'Hennezel, O., P. Pichat, and D.F. Ollis (1998). Benzene and toluene gas-phase photocatalytic degradation over $H_2O$ and HCL pretreated $TiO_2$: by-products and mechanisms. J. Photochem. Photobiol. A: Chem., 118, 197-204
  8. Fu, X., W.A. Zeltner, and M.A. Anderson (1995) The gas-phase photocatalytic mineralization of benzene on porous titania-based catalysts. Appl. Catal., B 6, 209-224
  9. Heavner, D.L., W.T. Morgan, and M.W. Ogden (1995) Determination of volatile organic compounds and ETS apportionment in 49 homes. Environ. Int., 21, 3-21
  10. Higgins, C.E., W.H. Greist, and G. Olerich (1983) Applications of Tenax trapping to cigarrete smoking. J. Assoc. Off. Anal. Chem., 66, 1074-1083
  11. Ibusuki, T. and K. Takeuchi (1986) Toluene oxidation on UV-jrradiated titanium dioxide with and without $O_2$,$NO_2$ or $H_2O$ at ambient temperature. Atmos. Environ., 20, 1711-1715
  12. IIgen, E., N. Karfich, K. Levsen, J. Angerer, P. Schneider, J. Heinrich, H. Wichmann, L. Dunemann, and J. Begerow (2001) Aromatic hydrocarbons in the atmospheric environment: Part I. Indoor versus outdoor sources, the influence of traffic. Atmos. Environ., 35, 1235-1252
  13. Jacoby, W.A., D.M. Blake, R.D. Noble, and C.A. Koval (1995) Kinetics of the oxidation of trichloroethylene in air via heterogeneous photocatalysis. J. Catal., 157, 87-96
  14. Jacoby, W.A., D.M. Blake, J.A. Fennell, J.E. Boulter, L.M. Vargo, M.C. George, and S.K. Dolberg (1996) Heterogeneous photocatalysis for control of volatile organic compounds in indoor air. J. Air & Waste Manage. Assoc., 46, 891-898
  15. Jeong, C.H., J.N. Suh, S.T. Kim, and K.C. Choi (2000) A study on the photocatalytic oxidation of trichloroethylene in air. J. Kor. Soc. Atmos. Environ., 16, 521-528
  16. Jo, W.K. and J.W. Oh (2001) Exposure to methyl tertiary butyl ether and benzene in close proximity to service stations. J. Air & Waste Manage. Assoc., 51, 1122-1128
  17. Kim, S.B., Y.M. Jo, and S.C. Hong (2001) A kinetic study on the photocatalytic degradation of gas-phase VOCs using $TiO_2$ catalyst. J. Kor. Soc. Atmos. Environ., 17, 117-124
  18. Lee, B.Y., S.W. Kim, and S.J. Choung (2001) The study on preparation parameters of $TiO_2$ catalyst for photodecomposition of ethanol as a VOC. J. Kor. Soc. Atmos Environ., 17,363-370
  19. Linsebigler, A., G. Lu, and J.T. Yates Jr (1996) CO photooxidation on $TiO_2$. J. Phys. Chem., 1000, 6631-6636
  20. Murabayashi, M., K. Itoh, J.S. Kim, E. Katori, K. Iguchi, K. Okamura, K. Kawashima, and R. Masuda (1994) Abstracts of Papers, The First International Conference on Advanced Oxidation technologies for Water and Air Remediation, London, Ontario, Canada; Elsevier: Amsterdam, June 25-30, pp. 335-336
  21. Obee, T.N. (1996) Photooxidation of sub-parts-per-million toluene and formaldehyde levels on titania using a glass-plate reactor. Environ. Sci. Technol., 30, 3578-3584
  22. Obee, T.N. and R.T. Brown (1995) $TiO_2$ photocatalysis for indoor air applications: effects of humidity and trace contaminant levels on the oxidation rates of formaldehyde, toluene, and 1, 3-butadiene. Environ. Sci. Technol. 29, 1223-1231
  23. Park, D.K., B.J. Kim, J.K. Lee, D.J. Byun, W.Y. Yoon, W.J. Lee, and J.Y. Sung (2000) Photocatalytic reactivity of titanioum dioxide in the removal of of benezene from air. J. Kor. Soc. Atmos. Environ., 16, 389-397
  24. Peral, J. and D.F. Ollis (1992) Heterogeneous photocatalytic oxidation of gas-phase organics for air purification,acetone, 1-butanol, butyraldehyde, formaldehyde and m-xylene oxidation. J. Catal., 136, 554-565
  25. Schneider, P., G. Lorinci, I.L. Gebefiigi, J. Heinrich, A. Kettrup, and H.E. Wichmann (1999) Vertical and horizontal variability of volatile organic compoundsin homes in Eastern Germany. J. Expos. Anal. Environ. Epidemiol., 9, 282-292
  26. Stevens, L., J.A. Lanning, L.G. Anderson, W.A. Jacoby, and N. Chornet (1998)Investigation of the photocatalytic oxidation of low-level carbonyl compounds. J. Air & Waste Manage. Assoc., 48, 979-984
  27. Suzuki, K. (1993) Photocatalytic Purification and treatment of Water and Air, Ollis DF, AI-Ekabi H, Eds.; Elsevier: Amsterdam, pp. 421-434
  28. Tancrede, M.R., W.L. Zeise, and E.A.C. Crouch (1987) The carcinogenic risk of some organic vapors indoors: a theoretical survey. Atmos. Environ., 21, 2187-2205
  29. United States Environmental Protection Agency (USEPA) (1990) Cancer risk from outdoor exposure to airtoxics. PA-450/1-90-004a
  30. Vorontsov, A.V., E.N. Savinov, G.B. Barannik, V.N. Troitsky, and V.N. Parmon (1997) Quantitative studies on the heterogeneous gas-phase photooxidation of CO and simple VOCs by air over $TiO_2$. Cat. Today, 39, 207-218
  31. Wallace, L.A., E.D. Pellizzari, T.D. Hartwell, V. Davis, L.C. Michael, and R.W. Whitmore (1989) The influence of personal activities on exposure to volatile organic compounds. Environ. Res. 50, 37-55
  32. Wallace, L., W. Nelson, R. Ziegenfus, E. Pellizzari, L. Michael, R. Whitmore, H. Zelon,T. Hartwell, and R. Perritt (1991) The Los Angeles TEAM study: personal exposures, indoor-outdoor air concentrations, and breath concentrations of 25 volatile organic compounds. J. Expos. Anal. Environ. Epidemiol., 1, 157-192
  33. Weedon, A.C. (1994) Abstracts of Papers, The First International Conference on Advanced Oxidation technologies for Water and Air Remediation, London, Ontario, Canada; Elsevier: Amsterdam; June 25-30, 127pp