DOI QR코드

DOI QR Code

황해와 한국연안해역 표층퇴적물중 Sb과 As의 농도분포특성

The distribution characteristics of Sb and As in the surface sediment from the Yellow Sea and the coastal areas of Korea

  • 발행 : 2003.10.01

초록

We report the distributions of Sb and As in the surface sediment of the Yellow Sea and the coastal areas of Korea. The mean concentrations of Sb and As range from 0.68 ppm to 1.01 ppm and from 7.4 ppm to 15.8 ppm, respectively, and show relatively the high concentrations at the coast of Weolseong in the East Sea for Sb and at the coast of Gadeok Island in the South Sea far As. This may be due to the anthropogenic input of these elements via river and atmosphere from industry complex and agriculture regions around the study areas. Because of the difference of clay to silt proportion, the correlation between silt plus clay contents and Sb, As in the coastal surface sediment of Korea is not shown, the concentrations of Sb and As vary widely for the sample in which the silt plus clay contents are the same. Therefore, we suggest that the distribution patterns of Sb and As in surface sediment of the Yellow Sea and the coastal areas of Korea are mainly controlled by the anthropogenic inputs and the sediment characteristics. On the other hand, the Sb concentrations are lower than those of the lowest effect level which is the standard of judgment for contamination, while the As concentrations are higher than those of the lowest effect level. This implies that the surface sediments of the Yellow Sea and the coastal areas of Korea are considerably contaminated for As.

키워드

참고문헌

  1. 방극진, 1995, 환경오염.유해화학물질 편람, 성인당, 1025pp
  2. Eskenazy, G. M., 1995, Geochemistry of arsenic and antimony in Bulgarian coals, Chem. Geol., 119, 239-254 https://doi.org/10.1016/0009-2541(94)00091-L
  3. Cutter, G. A. and L. S. Cutter, 1995, Behavior of dissolved antimony, arsenic and selenium in the Atlantic Ocean, Mar. Chem., 49, 295-306 https://doi.org/10.1016/0304-4203(95)00019-N
  4. Shotyk, W., A. K. Cheburkin, P. G. Appleby, A. Fankhauser and J. D. Kramers, 1996, Two thousand years of atmospheric arsenic, antimony, and lead deposition recorded in an ombrotrophic peat bog profile, Jura Mountains, Switzerland, Earth Planet. Sci. Lett., 145, EI-E7
  5. Byrd, J. T., 1988, The seasonal cycle of arsenic in estuarine and nearshore waters of the South Atlantic Bight, Mar. Chem., 25, 383-394 https://doi.org/10.1016/0304-4203(88)90118-1
  6. Michel, P., J. F. Chiffoleau, B. Averty, D. Auger and E. Chartier, 1999, High resolution profiles for arsenic in the Seine Estuary; Seasonal variations and net fluxes to the English Channel, Cont. Shelf Res., 19, 2041-2061 https://doi.org/10.1016/S0278-4343(99)00052-7
  7. Austin, L. S. and G. E. Millward, 1986, Atmosphere-coastal ocean fluxes of particulate arsenic and antimony, Cont. Shelf Res., 6, 459-474 https://doi.org/10.1016/0278-4343(86)90084-1
  8. Scudlark, J. R. and T. M. Church, 1988, The atmospheric deposition of arsenic and association with acid precipitation, Atmo. Environ., 22, 937-943 https://doi.org/10.1016/0004-6981(88)90271-5
  9. Gao, A. G., 1997, Element geochemistry of the sediment over an hydrothermally active area within the Middle Okinawa Trough, Yellow Sea Res., 7, 65-82
  10. Pierce, M. L. and C. B. Moore, 1982, Adsorption of arsenic and arsenate on amorphous iron hydroxide, Water Res., 16, 1247-1253 https://doi.org/10.1016/0043-1354(82)90143-9
  11. Whalley, C., S. Rowlatt, M. Bennett and D. Lovell, 1999, Total arsenic in sediments from the western North Sea and the Humber Estuary, Mar. Poll. Bull., 35, 394-400
  12. Crecelius, E. A., 1975, The geochemical cycle of arsenic in Lake Washington and its relation to other elements, Lirnnol. Oceanogr., 20, 441-451 https://doi.org/10.4319/lo.1975.20.3.0441
  13. Zhao, Y. and M. Yan, 1994, Geochemistry of sediments of the China Shelf Seas, Science Press, 203pp
  14. Leoni, L. and F. Sartori, 1997, Heavy metals and arsenic distributions in sediments of the Elba-Argentario Basin, southern Tuscany, Italy, Environ. Geol., 32, 83-92 https://doi.org/10.1007/s002540050196
  15. Filella, M., N. Belzile and Y. W. Chen, 2002, Antimony in the environment; a review focused on natural waters I. Occurrence, Earth-Sci. Rev., 57, 125-176 https://doi.org/10.1016/S0012-8252(01)00070-8
  16. Ellwood, M. J. and W. A. Maher, 2003, Measurement of arsenic species in marine sediments by high-performance liquid chromatography inductively coupled plasma mass spectrometry, Anal. Chim. Acta., 477, 279-291 https://doi.org/10.1016/S0003-2670(02)01414-9
  17. Measures, C. J. and J. D. Burton, 1980, The vertical distribution and oxidation states of dissolved selenium in the northeast Atlantic Ocean and their relationship to biological processes, Earth Planet. Sci. Lett., 46, 385-396 https://doi.org/10.1016/0012-821X(80)90052-7
  18. Mandal, B. K. and K. T. Suzuki, 2002, Arsenic round the world: a review, Talanta, 58, 201-235 https://doi.org/10.1016/S0039-9140(02)00268-0
  19. Smedley, P. L. and D. G. Kinniburgh, 2002, A review of the source, behaviour and distribution of arsenic in natural waters, Appl. Geochem., 17, 517-568 https://doi.org/10.1016/S0883-2927(02)00018-5
  20. Sullivan, K. A. and R. C. Aller, 1996, Diagenetic cycling of arsenic in Amazon shelf sediments, Geochim. Cosmochim Acta, 9, 1465-1477
  21. Gebel, T., 1997, Arsenic and antimony: comparative approach on mechanistic toxicology, Chem.-Biol. Interact., 107, 131-144 https://doi.org/10.1016/S0009-2797(97)00087-2
  22. 이동수, 1989, 대기를 통해 황해로 유입되는 오염물질의 부하량 측정에 관한 연구 ( I ), 한국해양연구소, 58pp
  23. 양동범, 1995, 황해의 해양오염조사 및 대책연구 (제1단계 3차년도 단계보고서), 한국해양연구소, 299pp
  24. Choi, M. S., J. H. Chun, H. J. Woo and H. I. Yi, 1999, Change of heavy metals and sediment facies in surface sediments of the Shihwa Lake, J. Korean Environ. Sci. Soc., 8, 593-600
  25. 山重 隆, 1998, 大氣中 金屬元素分析法, 資源環境對策, 34, 1282-1288
  26. Bettinelli, M., S. Spezia, U. Baroni and G. Bizzari, 1998, Microwave oven digestion of power plant emission and ICP-MS determination of trace elements, At. Spectrosc., 19, 73-79
  27. Martin, J. M. and M. Whitfield, 1983, The significance of the river input of chemical elements to the ocean, In: Tracer metals in seawater, edited by C. S. Wong, E. A. Royle. K. W. Bruland, J. D. Burton and E. D. Goldberg, Plenm, 265-296pp
  28. Park, Y A. and B. K Khim, 1992, Origin and dispersal of recent clay minerals in the Yellow Sea, Mar. Geol., 104, 205-213 https://doi.org/10.1016/0025-3227(92)90095-Y
  29. Zhang, J, W. W. Huang, S. M. Liu, M. G. Liu, Q. Yu and J. H. Wang, 1992, Transport of particulate heavy metals towards the China Sea: a preliminary study and comparison, Mar. Chem., 40, 161-178 https://doi.org/10.1016/0304-4203(92)90021-2
  30. Papakostidis, G., A. P. Grimanis, D. Zafiropoulos, G. B. Griggs and T. S. Hopkins, 1975, Heavy metlas in sediments from the Athens sewage outfall area, Mar. Pollut. Bull., 6, 136-139 https://doi.org/10.1016/0025-326X(75)90170-8
  31. Grimanis, A. P., M. Vassilaki-Grimani and G. B. Griggs, 1977, Pollution studies of trace elements in sediments from the upper Saronikos Gulf, Greece, J. Radioanal. Chem., 37, 761-763 https://doi.org/10.1007/BF02519388
  32. Mok, W. M. and C. M. Wai, 1990, Distribution and mobilization of arsenic and antimony species in the Coeur D'Alene River, Idaho, Environ. Sci. Technol., 24, 102-108 https://doi.org/10.1021/es00071a012
  33. Ha, J. S., 2000, Sediment characteristics and depositional environment of the Nakdong River Estuary and adjacent coastal area, M. D. Thesis, Pukyong National University, Busan, 92pp
  34. Park, S. C. and D. G. Yoo, 1988, Depositional history of Quanternary sediments on the continental shelf off the southeastern coast of Korea, Mar. Geol., 79, 65-75 https://doi.org/10.1016/0025-3227(88)90157-0
  35. Mirlean, N., V. E. Andrus, P. Baisch, G. Griep and M. R. Casartelli, 2003, Arsenic pollution in Patos Lagoon estuarine sediments, Brazil, Mar. Poll. Bull., In press
  36. Choi, D. L., J. K. Oh, C. W. Lee and H. J. Woo, 1997, High-resolution seismic characteristics of the Holocene mud deposits in the southeast innershelf, Korea, The Sea-J Korea Soc. Oceanogr., 2, 8-13
  37. Kim, G. Y., D. C. Kim, Y. K. Seo, S. C. Park, J. H. Choi and J. C. Kim, 1999, Physical properties of mudbelt sediments in the southeastern inner shelf of Korea, The Sea-J. Korea Soc. Oceanogr., 4, 338-348
  38. Ainsworth, N., J. A. Cooke and M. S. Johnson, 1990, Distribution of antimony in contaminated grassland: I. Vegetation and soils, Environ. Pollut., 65, 65-77 https://doi.org/10.1016/0269-7491(90)90165-9
  39. Asami, T., M. Kubota and S. Saito, 1992, Simultaneous determination of antimony and bismuth in soils by continuous hydride generation-atomic absorption spectrometry, Water, Air, Soil Pollut., 62, 349-355 https://doi.org/10.1007/BF00480266
  40. Grousset, F. E., C. R. Quetel, B. Thomas, O. F. X. Donard, C. E. Lambert, F. Guillard and A. Monaco, 1995, Anthropogenic vs. lithogenic origins of trace elements (As, Cd, Pb, Rb, Sb, Sc, Sn, Zn) in water column particles: northwestern Mediterranean Sea, Mar. Chem., 48, 291-310 https://doi.org/10.1016/0304-4203(94)00056-J
  41. Francesconi, K. and J. Edmonds, 1997, Arsenic and marine organisms. Advan, Inorgan. Chem., 44, 147-189
  42. DEC, 1991, Technical guidance for screening contaminated sediments. New York State Department of Environmental Conservation, New York, NY, 38pp
  43. CCME, 2001, Canadian sediment quality guideline for the protection of aquatic life. Canadian Council of Ministers of the Environment, Winnipeg, 12pp
  44. Long, E. R. and L. G. Morgan, 1990, The potential for biological effects of sediment-sorbed contaminants tested in the national states and trends program. National Oceanic Atmospheric Administration(NOAA) Technical Memorandum No.5, OMA52, NOAA National Ocean Service, Seattle, Washington, 175pp
  45. Persaud, D., R. jaagumagi and A. Hayton, 1992, Guidances for the protection and management of aquatic sediment quality in Ontario. Ontario Ministry of the Environment, Queen's Printer for Ontario, 32pp

피인용 문헌

  1. Geochemical Characteristics of Intertidal Surface Sediments along the Southwestern Coast of Korea vol.43, pp.2, 2010, https://doi.org/10.5657/kfas.2010.43.2.146
  2. Evaluation of Heavy Metal Contamination in Intertidal Surface Sediments of Coastal Islands in the Western Part of Jeollanam Province Using Geochemical Assessment Techniques vol.44, pp.6, 2011, https://doi.org/10.5657/KFAS.2011.0772