RF 스퍼터링법에 의한 SCT 박막의 제조 및 특성

Fabrication and Properties of SCT Thin Film by RF Sputtering Method

  • 발행 : 2003.10.01

초록

The (S $r_{0.85}$C $a_{0.15}$)Ti $O_3$(SCT) thin films were deposited on Pt-coated electrode(Pt/TiN/ $SiO_2$/Si) using RF sputtering method according to the deposition condition. The optimum conditions of RF power and Ar/ $O_2$ ratio were 140[W] and 80/20, respectively. Deposition rate of SCT thin films was about 18.75[$\AA$/min] at the optimum condition. The composition of SCT thin films deposited on Si substrate is close to stoichiometry (1.102 in A/B ratio). The capacitance characteristics had a stable value within $\pm$4[%]. The drastic decrease of dielectric constant and increase of dielectric loss in SCT thin films were observed above 200[kHz]. SCT thin films used in this study showed the phenomena of dielectric relaxation with the increase of frequency.ncy.

키워드

참고문헌

  1. Susumu Nishigaki, Kanji Murano, and Akio Ohkoshi, 'Dielectric Properties of Ceramics in the system $(Sr_{0.5}Pb_{0.25}Ca_{0.25})TiO_3-Bi_2O_33TiO_2$ and Their Applications in a High-Voltage Capacitor', J. Am. Ceram. Soc., Vol. 65(11), pp. 554-560, 1982 https://doi.org/10.1111/j.1151-2916.1982.tb10781.x
  2. D. W. Hoffman, and J. A. Thorton, 'Internal Stresses in Cr, Mo, Ta, and Pt Films Deposited by Sputtering from a Planar Magnetron Sources', J. Vac. Sci.&Technol., Vol.20(3), pp.355-358, 1982 https://doi.org/10.1116/1.571463
  3. S. Matsubara, S. Miura, Y. Miyasaka, and N. Shohata, 'Preparation of epitaxial $ABO_3$ Perovskite-type Oxide Thin Films on a(100) )$MgAl_2\;O_4/Si$ Substrate', J. Appl. Phys., Vol.66(12), pp.5826-5832, 1989 https://doi.org/10.1063/1.343654
  4. Yoshio Abe, Midori Kawamura, 'Dielectric Properties of SrTiO₃Capacitor Using TIN Bottom Electrode and Effects of $SrTiO_3$ Film Thickness', Jpn. J. Appl. Phys., Vol.36. pp.5175-5178, 1997 https://doi.org/10.1143/JJAP.36.5175
  5. J. S. Kim, C. N. Cho, and C. H. Kim, 'Fabrication and Properties of $(Sr_{1-X}Ca_x)TiO_3$ Ceramic Thin Film', ICEE 2002, Vol.III, pp.1179-1182, 2002
  6. C. A. T. Salama and E. Siciunas, 'Characteristics of rf Sputtered Barium Titanate Films on Silicon', J. Vac. Sci.&Technol., Vol.9(1), pp.91-96, 1971
  7. Neung-Ho Cho, Seunf-Hee Nam, 'Preparation of strontium titanate thin film on Si substrate by radio frequency magnetron sputtering', J. Vac. Sci.&Technol., A 10(1), pp.87-91, 1992 https://doi.org/10.1116/1.578071
  8. D. X. LU, E. M. W. WONG, 'Preparation and ferroelectric properties of lead zirconate titanate thin films by RF magnetron sputtering', INT. J. ELECTRONICS, Vol.83(6), pp.805-815, 1997 https://doi.org/10.1080/002072197135076
  9. Tae Song Kim and Chong Hee Kim, 'Structural and electrical properties of rf magnetron-sputtered $Ba_{1-x}Sr_xTiO_3$ thin films on indium-tin-oxide-coated glass substrate', J. Appl. Phys., Vol.75(12), pp.7998-8003, 1994 https://doi.org/10.1063/1.356537
  10. A. N. Gubkin, A. J. Kashtanova, G. I. Skanavi, 'Dielectric Properties of Strontium Bismuth Titanates at Low Temperature', Fiz. Tverd.Teia., Vol.34, pp.1110-1116, 1961
  11. R. Wernicke, 'Two-Layer Model Explaining the Properties of $SrTiO_3$ Boundary Layer Capacitior', Advances in Ceramics, Vol.1, pp.272-281, Edited by L. M. Levinson and D. C. Hill, 1981
  12. P. E. C. Franken, M. P. A. Vigers et al., 'Microstructure of $SrTiO_3$ Boundary-Layer Capacitor Material', J. Am. Ceram. Soc., Vol.64(12), pp.687-690, 1981 https://doi.org/10.1111/j.1151-2916.1981.tb15886.x
  13. Yoshitaka Nakano et al., 'Investigation of interface states in (Sr, Ca)YiO3-xbased Ceramics', J. Appl. Phys., Vol.70(3), pp.1539-1547, 1991 https://doi.org/10.1063/1.349570
  14. Shigeru waku et al., 'Classification and Dielectrics of the Boundary Layer Ceramic Dielectrics', Rev. Elect. Commun. Lab., Vol.19, pp.665-679, 1971
  15. Shang Y. Hou, J. Kwo, R. K. Watts, et al., 'STRUCTURAL AND DIELECTRIC PROPERTIES OF $Ba_{0.5}Sr_{0.5}TiO_3$ THIN FILMS GROWN ON Si BY OFF-AXIS SPUTTERING', Integrated Ferroelectrics, Vol.10, pp.343-350, 1995 https://doi.org/10.1080/10584589508012292
  16. W. Johnson, L. E. Cross, F. A. Hummel, 'Dielectric Relaxation in Strontium Titanates Containing Rare-Earth Lons', J. Appl. Phys., Vol.41, pp.2828-2833, 1970 https://doi.org/10.1063/1.1659323