Macromolecular Research

  • 제11권2호
  • /
  • Pages.80-86
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  • 2003
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  • 1598-5032(pISSN)
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  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Polymerization of Bis(3-trimethylsilyl-2-propynyl)ether and Its Copolymerization with Diethyl Dipropargylmalonate

  • Gal, Yeong-Soon (Polymer Chemistry Laboratory, College of General Education, Kyungil University) ;
  • Jin, Sung-Ho (Department of Chemistry Education, Pusan National University) ;
  • Lee, Hyung-Jong (Zenphotonics, Rm 303, K-MAC BLD.) ;
  • Kim, Sung-Hyun (Electronic Material Research Center, LG Chem) ;
  • Kim, Won-Chul (Department of Textile and Fashion Technology, Kyungil University) ;
  • Park, Sam-Kwon (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • 발행 : 2003.04.01
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초록

The polymerization of a cyclopolymerizable disubstituted dipropargyl ether, his(3-trimethylsilyl-2-propynyl)ether (BTPE), was attempted by various transition metal catalysts. The yield for the polymerization of BTPE was generally low, which is possibly due to the steric hindrance of bulky substituents. In general, the catalytic activities of Mo-based catalysts were found to be greater than those of W-based catalysts. The highest yield was obtained when the MoCl$_{5}$,-EtAlCl$_2$(1:2) catalyst system was used. The copolymerization of BTPE and diethyl dipropargylmalonate yielded a random copolymer with conjugated polymer backbone. However the polymers were partially desilylated, depending on the reaction conditions. The thermal and morphological properties of the resulting polymers were also discussed.d.

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