Macromolecular Research

  • 제11권1호
  • /
  • Pages.69-72
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  • 2003
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  • 1598-5032(pISSN)
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  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

The First Synthesis of a Transition Metal-Catalyzed Homopolymer Having Pendent t-Boc-Protected Quinizarin for Patterned Fluorescence Images

  • Jimmy Yoo (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Lee, Jae-Hyoung (Department of Advanced Materials Engineering, Korea Institute of Science and Technology) ;
  • Iwhan Cho (Department of Advanced Materials Engineering, Korea Institute of Science and Technology) ;
  • Ahn, Kwang-Duk (Functional Polymer Laboratory, Korea Institute of Science and Technology) ;
  • Kim, Jong-Man (Department of Chemical Engineering, Hanyang University)
  • 발행 : 2003.02.01
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초록

A homopolymer having pendent t-Boc-protected quinizarin moieties has been prepared for patterned fluorescence images. The homopolymer P(t-BQN (2-norbornenylmethyl di-tert-butoxycarbonylquinizarin)) 5 was prepared by palladium-catalyzed addition polymerization. The t-Boc-protecting groups of the polymer were efficiently removed during chemical amplification process and revealed original properties of quinizarin, allowing patterned fluorescence images in the polymer film.

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