Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond

수소 결합에 의한 삼차원의 Copper(II) 거대고리 착물과 2,5-Pyridinedicarboxylate와의 자기조립

  • Ki-Young Choi (Department of Chemistry Education, Kongju National University) ;
  • Haiil Ryu (Department of Chemistry Education, Kongju National University) ;
  • Yong-Son Kim (Department of Chemistry Education, Kongju National University)
  • 최기영 (공주대학교 사범대학 화학교육과) ;
  • 류해일 (공주대학교 사범대학 화학교육과) ;
  • 김용선 (공주대학교 사범대학 화학교육과)
  • Published : 2003.04.20
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Abstract

The reaction of $[Cu(L)]Cl_2{\cdot}H_2O(L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0^{1.18},0^{7.12}]docosane)$ with 2,5-pyridinedicarboxylate(pdc) led to the formation of $[Cu(L)(H_2O)](pdc){\cdot}6H_2O(1)$. The structure was characterized by X-ray crystallography and spectroscopic method. The coordination geometry around the copper atom is a distorted square-pyramid with four secondary amines of the macrocycle occupying the basal sites and a water molecule at the axial position. Intermolecular hydrogen bonds in 1 form a three-dimensional molecular network.

$[Cu(L)]Cl_2{\cdot}2H_2O(L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0^{1.18},0^{7.12}]docosane)$과 2,5-pyridinedicarboxylate(pdc)의 반응으로부터 $[Cu(L)(H_2O)](pdc){\cdot}6H_2O(1)$가 합성되었다. 화합물 1의 구조가 X-ray 회절법 및 분광학적 방법으로 규명되었다. 중심 copper 원자는 거대고리 리간드로부터 4개의 이차 아민과 축방향 위치의 물분자로 결합된 약간 일그러진 사각뿔 구조를 갖는다. 또한 분자간 수소결합은 삼차원의 분자구조를 형성한다.

Keywords

References

  1. Claessens, C. G.; Stoddart, J. F. J. Phys. Org. Chem.1997, 10, 254. https://doi.org/10.1002/(SICI)1099-1395(199705)10:5<254::AID-POC875>3.0.CO;2-3
  2. Subramanian, S.; Zaworotko, M. J. Coord. Chem. Rev.1994, 137, 357. https://doi.org/10.1002/(SICI)1521-3773(19990517)38:10<1405::AID-ANIE1405>3.0.CO;2-H
  3. Aaker y, C. B. Acta Crystallogr. 1997, B53, 569. https://doi.org/10.1021/ic980243g
  4. Videnova-Adrabi?ka, V. J. Mol. Struct. 1996, 374, 199. https://doi.org/10.1016/0022-2860(95)08975-6
  5. Desiraju, G. R. Chem. Commun. 1997, 1475. https://doi.org/10.1016/S1387-7003(99)00164-1
  6. Clegg, R. S.; Hutchison, J. E. J. Am. Chem. Soc. 1999, 121, 5319. https://doi.org/10.1021/ja9901011
  7. Burrows, A. D.; Mingos, D. M. P.; White, A. J. P.; Williams, D. J. J. Chem. Soc., Chem. Commun. 1996, 97.
  8. Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Rychlewska, U. Inorg. Chem. 1994, 33, 359. https://doi.org/10.1021/ic00080a027
  9. Cirujeda, J.; Mas, M.; Molins, E.; De Panthou, F. L.; Laugier, J.; Park, J. C.; Paulsen, C.; Ray, C.; Rovira, C.; Veciana, J. J. Chem. Soc., Chem. Commun. 1995, 709.
  10. Choi, H. J.; Lee, T. S.; Suh, M. P. Angew, Chem. Int. Ed. 1999, 38, 1405. https://doi.org/10.1023/A:1022894318159
  11. Bernhardt, P. V.; Hayes, E. J. Inorg. Chem. 1998, 37, 4214. https://doi.org/10.1021/ic980243g
  12. Bernhardt, P. V. Inorg. Chem. 1999, 38, 3483. https://doi.org/10.1016/0010-8545(94)03008-E
  13. Choi, K.-Y.; Suh, I.-H.; Hong, C. P. Inorg. Chem. Commu. 1999, 2, 604. https://doi.org/10.1016/S1387-7003(99)00164-1
  14. Kang, S.-G.; Kweon, J. K.; Jung, S. K. Bull. Korean Chem. Soc. 1991, 12, 483. https://doi.org/10.1021/ja00749a020
  15. Choi, K.-Y.; Kim, J. C.; Hensen, W. P.; Suh, I.-H.; Choi, S.-S. Acta Crystallogr. 1997, C52, 2166.
  16. Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467. https://doi.org/10.1016/0022-2860(95)08975-6
  17. Sheldrick, G. M. SHELXL 97, Program for the Refinement of Crystal Structures; University of G ttingen: Germany, 1997.
  18. Choi, K.-Y. J. Chem. Crystallogr. 1998, 28, 875. https://doi.org/10.1021/ja9901011
  19. Choi, K.-Y.; Kim, M.-J.; Kim, D.-S.; Kim, Y.-S.; Kim, J.-H.; Ryu, H.; Lim, Y.-M.; Kang, S.-G.; Shin, U.-S.; Lee, K.-C.; Hong, C.-P. Bull. Korean Chem. Soc. 2002, 23, 1321. https://doi.org/10.5012/bkcs.2002.23.9.1321
  20. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed.; John Wiley and Sons: New York, 1986. https://doi.org/10.1021/ic00080a027
  21. Nielson, D. O.; Larsen, M. L. Willett, R. D.; Legg, J. I. J. Am. Chem. Soc. 1971, 93, 5079. https://doi.org/10.1021/ja00749a020

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