Bulletin of the Korean Chemical Society

  • 제24권10호
  • /
  • Pages.1449-1454
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  • 2003
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Description of Temperature Dependence of Critical Micelle Concentration

  • Kim, Hong-Un (Department of Chemical Engineering, Chung-Ang University) ;
  • Lim, Kyung-Hee (Department of Chemical Engineering, Chung-Ang University)
  • 발행 : 2003.10.20
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초록

A new equation has been derived on the basis of ${\delta}G^o$ = -RT lnK, linear behavior of the enthalpy of micellization with temperature, and the Gibbs-Helmholtz relation. It describes correctly the dependence of critical micelle concentration $(X_{CMC})$ on temperature and has yielded excellent fitting results for various surfactant systems. The new equation results in the linear behavior of the entropy of micellization with temperature and accounts for the compensation phenomena observed for the micellization in aqueous solutions, along with the linear dependence of the enthalpy of micellization on temperature. These results imply that the new equation of $X_{CMC}(T)$ accounts for the temperature dependence of CMC correctly.

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참고문헌

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