Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Femtosecond Coherent Spectroscopic Study of Zn(II)porphyrin Using Chirped Ultrashort Pulses

  • Yoon, Min-Chul (National Creative Research Initiatives Center for Ultrafast Optical Characteristics Control andDepartment of Chemistry, Yonsei University) ;
  • Song, Jae-Kyu (National Creative Research Initiatives Center for Ultrafast Optical Characteristics Control andDepartment of Chemistry, Yonsei University) ;
  • Cho, Sung (National Creative Research Initiatives Center for Ultrafast Optical Characteristics Control andDepartment of Chemistry, Yonsei University) ;
  • Kim, Dong-Ho (National Creative Research Initiatives Center for Ultrafast Optical Characteristics Control andDepartment of Chemistry, Yonsei University)
  • Published : 2003.08.20
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Abstract

We have investigated femtosecond coherent vibrational motions of Zn(II)-5,15-diphenylporphyrin in toluene using chirp-controlled ultrashort pulses. The oscillatory features superimposed on the temporal profiles of the pump-probe transient absorption signal are affected by the chirping and energy of excitation pulses. Using chirp- and excitation energy-controlled femtosecond pulses, we are able to obtain information on the structural changes between the electronic ground and excited states based on a comparative analysis of the Fouriertransformed frequency-domain spectra retrieved from the oscillatory components with the ground state resonance Raman spectra and normal mode calculations.

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References

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