Effects of chemical reaction on the polishing rate and surface planarity in the copper CMP

  • Kim, Do-Hyun (Center for Ultramicrochemical Process Systems, Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology) ;
  • Bae, Sun-Hyuk (Center for Ultramicrochemical Process Systems, Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology) ;
  • Yang, Seung-Man (Center for Ultramicrochemical Process Systems, Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology)
  • 발행 : 2002.06.01

초록

Chemical mechanical planarization (CMP) is the polishing process enabled by both chemical and mechanical actions. CMP is used in the fabrication process of the integrated circuits to achieve adequate planarity necessary for stringent photolithography depth of focus requirements. And recently copper is preferred in the metallization process because of its low resistivity. We have studied the effects of chemical reaction on the polishing rate and surface planarity in copper CMP by means of numerical simulation solving Navier-Stokes equation and copper diffusion equation. We have performed pore-scale simulation and integrated the results over all the pores underneath the wafer surface to calculate the macroscopic material removal rate. The mechanical abrasion effect was not included in our study and we concentrated our focus on the transport phenomena occurring in a single pore. We have observed the effects of several parameters such as concentration of chemical additives, relative velocity of the wafer, slurry film thickness or ash)tract ratio of the pore on the copper removal rate and the surface planarity. We observed that when the chemical reaction was rate-limiting step, the results of simulation matched well with the experimental data.

키워드

참고문헌

  1. J. Electrochem. Soc. v.142 no.11 Chemicalmechanical polishing in semidirect contact mode Bhushan, M.;R. Rouse;J. E. Lukens https://doi.org/10.1149/1.2048422
  2. Korea-Australia Rheology Journal v.12 no.3/4 Shear-induced microstructure and rheology of cetylpyridinium chloride/sodium salicylate micellar solutions Choi, D.-G.;W.-J. Kim;S.-M. Yang
  3. J. Non-Crystalline Solid v.120 Chemical Processes in Glass Polishing Cook, L.M. https://doi.org/10.1016/0022-3093(90)90200-6
  4. International Journal for Numerical Method in Engineering v.10 Frontal solution program for unsymmetric matrices Hood, P. https://doi.org/10.1002/nme.1620100209
  5. Korea-Australia Rheology Journal v.13 no.1 Migration in concentrated suspension of spherical particles dispersed in polymer solution Kim, C.
  6. Tribology Transactions, Soc. Tribologists and Lubrication Eng. v.41 no.4 Mechanisms of chemical-mechanical polishing of SiO2 dielectric on integrated circuits Levert, J. A.;F. M. Mess;R. E. Salant;S. Danylukand;A. R. Baker
  7. J. Soc. Glass Tech. v.11 no.44 The theory and design of plate glass polishing machine Preston, F. W.
  8. J. Electrochem. Soc. v.141 no.7 Feature-scale fluid based erosion modeling for chemical-mechanical polishing Runnels, S. R. https://doi.org/10.1149/1.2055024
  9. J. Electronic. Mat. v.25 no.10 Advances in physically based erosion simulators for CMP Runnels, S. R. https://doi.org/10.1007/BF02655578
  10. J. Electronic Materials v.25 no.10 Eletrochemical effects in the chemicalmechanical polishing of copper for integrated circuits Sainio, C. A.;D. J. Duquette;J. M. Steigerwald;S. P. Murarka https://doi.org/10.1007/BF02655581
  11. J. Electrochem. Soc. v.141 no.6 Tribology analysis of chemical-mechanical polishing Runnels, S. R.;L. M. Eyman https://doi.org/10.1149/1.2054985
  12. Chemical mechanical planarization of microelectronic materials Steigerwald, J. M.;S. P. Murarka;R. J. Gutmann
  13. J. Electrochem. Soc. v.146 no.11 Transport phenomena in chemical mechanical polishing Subramanian, R.;L. Zhang;S. V. Babu https://doi.org/10.1149/1.1392626
  14. J. Electrochem. Soc. v.146 no.2 Two-dimensional wafer-scale chemical mechanical planarization models based on lubrication theory and mass transport Sundararajan, S.;D. G. Tharkurta;D. W. Schwendeman;S. P. Murarka;W. N. Gill https://doi.org/10.1149/1.1391678
  15. VLSI Technology Sze, S.M.
  16. Korea-Australia Rheology Journal v.12 no.3/4 Three-dimensional numerical simulation of nonisothermal coextrusion process with generalized Newtonian fluids Sunwoo, K. B.;S. J. Park;S. J. Lee;K. H. Ahn;S. J. Lee
  17. J. App. Electrochem. v.20 no.3 A masstransfer model for the autocatalytic dissolution of a rotating copper disk in oxygen saturated ammonia solutions Zembura, Z.;A. Piotrowski;A. Z. Kolend https://doi.org/10.1007/BF01076042