SiC 전도성 세라믹 복합체의 특성에 미치는 TiB$_2$의 영향

Effect of TiB$_2$on Properties of SiC Electroconductive Ceramic Composites

  • 발행 : 2002.04.01

초록

The mechanical and electrical properties of the pressureless sintered SiC-TiB$_2$electroconductive ceramic composites were investigated as functions of the transition metal of TiB$_2$. The result of phase analysis for the SiC-TiB$_2$ composites by XRD revealed $\alpha$-SiC(6H), TiB$_2$, and YAG(Al$_{5}$Y$_3$O$_{12}$) crystal phases. The relative density showed the lowest 84.8% for the SiC-TiB$_2$composites added with 39vol.%TiB$_2$. Owing to crack deflection, crack bridging and YAG of fracture toughness mechanism, the fracture toughness showed the highest value of 7.8 MPa.m$^{1}$2/ for composites added with 39vol.%TiB$_2$under a pressureless annealing at room temperature. The electrical resistivity of the SiC-27vol.%TiB$_2$ composites was negative temperature coefficient resistance(NTCR), and the electrical resistivity of the besides SiC-27vol.%TiB$_2$composites was all positive temperature coefficient resistance(PCTR) in the temperature range of $25^{\circ}C$ to $700^{\circ}C$.EX>.

키워드

참고문헌

  1. S. Prdchazka and R. M. Scanlan, 'Effect of Boron and Carbon on Sintering SiC,' J. Am. Ceram. Soc., Vol. 58, NO. 1-2, pp. 72, 1975 https://doi.org/10.1111/j.1151-2916.1975.tb18990.x
  2. F. F. Lange and T. K. gupta, 'Sintering of SIC with Boron Compounds,' J. Am. Ceram. Soc.,-Discussions and Note, Vol. 59, NO. 11-12, pp. 537-538, 1976 https://doi.org/10.1111/j.1151-2916.1976.tb09435.x
  3. Yukio Takeda, Kousuke Nakamura, Kunihiro Maeda and Yasuo Matsushita, 'Effects of Elemental Additives on Electrical Resistivity of Silicon Carbide Ceramics,' J. Am. Ceram. Soc., Vol. 70, No. 10, pp. c266-c267, 1987
  4. Do-Hyeong Kim and Chong Hee Kim, 'Toughening Behavior of Silicon Carbide with Additions of Yttria and Alumina,' J. Am. Ceram. Soc., Vol. 735, pp. 1431-1434, 1990 https://doi.org/10.1111/j.1151-2916.1990.tb05219.x
  5. Suresh Baskaran and John W. Halloran, 'Fibrous Monolithic Ceramics: II, Flexural Strength and Fracture Behavior of the Silicon Carbide/Graphite System,' Journal of the American Ceramic Society, Vol. 76, NO. 9, pp. 2217-2224, 1993 https://doi.org/10.1111/j.1151-2916.1993.tb07757.x
  6. Seung-Hyunk Yim, Yong-Deok Shin and Joon-Tae Song, 'The Properties of ${\beta}-SiC-TiB_2$ Electroconductive Ceramic Composites Densified by Liquid-Phase Sintering,' Trans. KIEE., Vol. 49C, No. 9, pp. 510-515, 2000
  7. Youg-Deok Shin, Jin-Young Ju and Mi-Lim Park, 'Manufacture and Properties of ${\beta}-SiC-TiB_2$ Composites Densified by Pressureless Annealing,' Trans. KIEE., Vol. 50C, No. 5, pp. 221-225, 2001
  8. Yiug-Deok Shin, Seung-Hyuk Yim and Joon-Tae Song, 'Properties of ${\beta}-SiC-TiB_2$ Electroconductive Ceramic Composites Densified by Liquid-Phase Sintering,' Trans. KIEE., Vol. 50C, No. 6, pp. 263-270, 2001
  9. Mi-Lim Park, Chul Whang, Yong-Dock Shin and Dong-Yoon Lee, 'Electrical Resistivity of the ${\beta}-SiC+39vol.%TiB_2$ Composites,' KIEEME Annual Spring Conference, pp. 15-18
  10. A. G. Evans and T. R. Wilshaw, 'Quasi-Static Solid Particle Demage in Brittle Solids-1. Observation Analysis and Implication,' Acta Metallurgica., Vol. 24, pp. 939-956, 1976 https://doi.org/10.1016/0001-6160(76)90042-0
  11. M. Ramulu and M. Taya, 'EDM machinability of SiCw/Al Composites,' Journal of Materials Science, Vol. 24, pp. 1103-1108, 1989 https://doi.org/10.1007/BF01148805
  12. Patricis A. Hoffman, 'Thermo Elastic Properties of Silicon Cabide-Titanium Diboride Particulate Composite,' M. S. Thesis, Department of Materials Science and Engineering, The Pennsylvania State University, 1992
  13. Jurgen Rodel, 'Interaction Between Crack Deflection and Crack Bridging,' Journal of the European Ceramic Society, Vol. 10, pp. 143-150, 1992 https://doi.org/10.1016/0955-2219(92)90027-B
  14. Seung-Hyuk Yim, Yong-Deok Shin, Jin-Young Ju, Se-Woon and Joon-Tae Song, 'properties of the ${beta}-SiC-TiB_2$ Composites with $Al_2O_3+Y_2O_3$ additives,' Trans. KIEE., Vol. 49C, No. 7, pp. 394-399, 2000