Bulletin of the Korean Chemical Society

  • 제23권11호
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  • Pages.1585-1589
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  • 2002
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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N-Anthracenylmethyl Calix[4]azacrowns as New Fluorescent Ionophores

  • Yang, Seung-H. ;
  • Shon, Ok-J. ;
  • Park, Ki-M. ;
  • Lee, Shim-S. ;
  • Park, Ho-J. ;
  • Kim, Moon-J. ;
  • Lee, Joung-H. ;
  • Kim, Jong-S.
  • 발행 : 2002.11.20
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초록

Two novel calixarene-based fluoroionophores were synthesized. Their conformations were confirmed to 1,3-alternate by X-ray crystal structures. From CHEF by blocking the PET mechanism in fluorescence spectra, we observed $In^{3+}$ and $Pb^{2+}$ selectivity over other metal ions. For $In^{3+}$ion, calix[4]-bis-azacrown-5 showed about 20 times more sensitive than calix[4]-mono-azacrown-5 because the source of the binding selectivity comes from the calixarene framework and azacrown ligand by controlling the fluorescence and PET mechanisms as-sociated with the amine moiety.

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참고문헌

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  3. N-Anthracenylmethyl Calix[4]azacrowns as New Fluorescent Ionophores vol.34, pp.16, 2003, https://doi.org/10.1002/chin.200316171
  4. Selective luminescence detection of cadmium(II) and mercury(II) utilizing sulfur-containing anthraquinone macrocycles (part 2) and formation of an unusual Hg22+-crown ether dimer via reduction of Hg(I vol.26, pp.6, 2002, https://doi.org/10.1016/j.poly.2006.10.046