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N-Anthracenylmethyl Calix[4]azacrowns as New Fluorescent Ionophores

  • Yang, Seung-H. ;
  • Shon, Ok-J. ;
  • Park, Ki-M. ;
  • Lee, Shim-S. ;
  • Park, Ho-J. ;
  • Kim, Moon-J. ;
  • Lee, Joung-H. ;
  • Kim, Jong-S.
  • Published : 2002.11.20

Abstract

Two novel calixarene-based fluoroionophores were synthesized. Their conformations were confirmed to 1,3-alternate by X-ray crystal structures. From CHEF by blocking the PET mechanism in fluorescence spectra, we observed $In^{3+}$ and $Pb^{2+}$ selectivity over other metal ions. For $In^{3+}$ion, calix[4]-bis-azacrown-5 showed about 20 times more sensitive than calix[4]-mono-azacrown-5 because the source of the binding selectivity comes from the calixarene framework and azacrown ligand by controlling the fluorescence and PET mechanisms as-sociated with the amine moiety.

Keywords

References

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