Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

3-Dimensional Terbium Coordination Polymers: [Tb4(NDC)6(H2O)5]·2H2O and [Tb2(BPDC)3(H2O)3]·H2O(NDC = 2,6-Naphthalenedicarboxylate; BPDC = 2,2'-Bipyridine-4,4'-dicarboxylate)

  • Min, Dong-Won (Department of Chemistry and School of Molecular Science (BK21),Sungkyunkwan University) ;
  • Lee, Soon-W. (Department of Chemistry and School of Molecular Science (BK21),Sungkyunkwan University)
  • Published : 2002.07.20
Download PDF
⟨ Previous Next ⟩

Abstract

Three-dimensional terbium coordination polymers with the formulas of [Tb4(NDC)6(H2O)5]${\cdot}$2H2O (1) and [Tb2(BPDC)3(H2O)3]${\cdot}$H2O (2) (NDC = 2,6-naphthalenedicarboxylate; BPDC = 2,2'-bipyridine-4,4'-dicarboxy-late) were prepared by hydrothermal reactions. Both compounds were structurally characterized by X-ray diffraction. Compound 1 has a polymeric structure that contains four distinct Tb metals. Three Tb metals have a square-antiprismatic structure, and the remaining one has a 9-coordinate, triply capped trigonal-prismatic structure. Compound 2 is also a polymer with two distinct Tb metals, both of which have a square-antiprismatic structure. The pyridine nitrogen atoms of the BPDC 2- ligand do not coordinate to the metal centers in compound 2.

Keywords

References

  1. Swieger, G. F.; Malefetse, T. J. Chem. Rev. 2000, 100, 3483. https://doi.org/10.1021/cr990110s
  2. Macdonald, J. C.; Dorrestein, P. C.; Pilley, M. M.; Foote, M. M.;Lundberg, J. L.; Henning, R. W.; Schultz, A. J.; Manson, J. L. J.Am. Chem. Soc. 2000, 122, 11692. https://doi.org/10.1021/ja002102v
  3. Li, H.; Eddaoudi, M.; OKeeffe, M.; Yaghi, O. M. Nature 1999,402, 276. https://doi.org/10.1038/46248
  4. Huang, X. Y. J. Coord. Chem. 1999, 47, 269. https://doi.org/10.1080/00958979908023059
  5. Braga, D.; Grepioni, F. Coord. Chem. Rev. 1999, 183, 19. https://doi.org/10.1016/S0010-8545(98)90172-2
  6. Reineke, T. M.; Eddaoudi, M.; OKeeffe, M.; Yaghi, O. M. Angew.Chem., Int. Ed. Engl. 1999, 38, 2590. https://doi.org/10.1002/(SICI)1521-3773(19990903)38:17<2590::AID-ANIE2590>3.0.CO;2-H
  7. Evans, O. R.; Xiong, R.-G.; Wang, Z.; Wong, G. K.; Lin, W.Angew. Chem., Int. Ed. Engl. 1999, 38, 536. https://doi.org/10.1002/(SICI)1521-3773(19990215)38:4<536::AID-ANIE536>3.0.CO;2-3
  8. Evans, O. R.; Wang, Z.; Xiong, R.-G.; Foxman, B. M.; Lin, W.Inorg. Chem. 1999, 38, 2969. https://doi.org/10.1021/ic990022q
  9. Blake, A. J.; Champness, N. R.; Hubberstey, P.; Li, W.-S.; Withersby,M. A.; Schröder, M. Coord. Chem. Rev. 1999, 183, 117. https://doi.org/10.1016/S0010-8545(98)00173-8
  10. Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed.Engl. 1999, 38, 2638. https://doi.org/10.1002/(SICI)1521-3773(19990917)38:18<2638::AID-ANIE2638>3.0.CO;2-4
  11. Yaghi, O. M.; Li, H.; Davis, C.; Richardson, D.; Groy, T. L. Acc.Chem. Res. 1998, 31, 474. https://doi.org/10.1021/ar970151f
  12. Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375. https://doi.org/10.1021/cr960091b
  13. Lin, W.; Evans, O. R.; Xiong, R.-G.; Wang, Z. J. Am. Chem. Soc.1998, 120, 13272. https://doi.org/10.1021/ja983415h
  14. Yaghi, O. M.; Davis, C. E.; Li, G.; Li, H. J. Am. Chem. Soc. 1997,119, 2861. https://doi.org/10.1021/ja9639473
  15. Abrahams, B. F.; Hoskins, B. F.; Michall, D. M.; Robson, R.Nature 1995, 374, 727. https://doi.org/10.1038/374727a0
  16. Gardner, G. B.; Venkataraman, D.; Moore, J. S.; Lee, S. Nature1995, 374, 792. https://doi.org/10.1038/374792a0
  17. Reineke, T. M.; Eddaoudi, M.; Fehr, M.; Kelley, D.; Yaghi, O. M.J. Am. Chem. Soc. 1999, 121, 1651. https://doi.org/10.1021/ja983577d
  18. Baggio, R.; Garland, M. T.; Perec, M.; Vega, D. Inorg. Chem.1996, 35, 2396. https://doi.org/10.1021/ic951078x
  19. Wang, S.; Pang, Z.; Smith, K. D. L.; Wagner, M. J. J. Chem. Soc.,Dalton Trans. 1994, 955.
  20. Min, D.; Yoon, S. S.; Lee, C. Y.; Suh, M.; Hwang, Y.-J.; Han, W.S.; Lee, S. W. Bull. Korean Chem. Soc. 2001, 22, 531.
  21. Min, D.; Yoon, S. S.; Lee, J. H.; Suh, M.; Lee, S. W. Inorg. Chem.Commun. 2001, 4, 297. https://doi.org/10.1016/S1387-7003(01)00197-6
  22. Min, D.; Yoon, S. S.; Lee, C. Y.; Han, W. S.; Lee, S. W. Bull.Korean Chem. Soc. 2001, 22, 1041.
  23. Min, D.; Yoon, S. S.; Jung, D. Y.; Lee, C. Y.; Kim, Y.; Han, W. S.;Lee, S. W. Inorg. Chim. Acta 2001, 324, 293. https://doi.org/10.1016/S0020-1693(01)00621-1
  24. Kim, H. J.; Min, D.; Hoe, H. S.; Lee, S. W. J. Korean Chem. Soc.2001, 45, 507.
  25. Min, D.; Yoon, S. S.; Lee, S. W. Inorg. Chem. Commun. 2002, 5,143. https://doi.org/10.1016/S1387-7003(01)00366-5
  26. Bruker, SHELXTL, Structure Determination Software Programs; Bruker Analytical X-ray Instruments Inc.: Madison, Wisconsin, USA, 1997.
  27. Pan, L.; Frydek, T.; Sander, M. B.; Huang, X.; Li, J. Inorg. Chem.2001, 40, 1271. https://doi.org/10.1021/ic001012o
  28. Mehrotra, R. C.; Bohra, R. Metal Carboxylates; Academic Press:New York, 1983.
  29. Gordon, A. J.; Ford, R. A. The Chemist's Companion: A Handbookof Practical Data, Techniques, and References; Wiley: NewYork, 1972.
  30. Ma, L.; Evans, O. R.; Foxman, B. M.; Lin, W. Inorg. Chem. 1999,38, 5837. https://doi.org/10.1021/ic990429v
  31. Ananias, D.; Ferreira, A.; Rocha, J.; Ferreira, P.; Rainho, J. P.;Morais, C.; Carlos, L. D. J. Am. Chem. Soc. 2001, 123, 5735. https://doi.org/10.1021/ja010244z

Cited by

  1. Synthesis, spectroscopic and thermal studies of 2,3-naphthalenedicarboxylates of rare earth elements vol.103, pp.1, 2011, https://doi.org/10.1007/s10973-010-0927-1
  2. Novel Luminescent Three-Dimensional Heterometallic Complexes with 2-Fold Interpenetrating (3,6)-Connected Nets vol.11, pp.5, 2011, https://doi.org/10.1021/cg101642j
  3. Water-Free Neodymium 2,6-Naphthalenedicarboxylates Coordination Complexes and Their Application as Catalysts for Isoprene Polymerization vol.51, pp.1, 2012, https://doi.org/10.1021/ic2019346
  4. A supramolecular copper(II) compound with double bridging water ligands: synthesis, crystal structure, spectroscopy, thermal analysis, and magnetism vol.38, pp.1, 2013, https://doi.org/10.1007/s11243-012-9656-6
  5. -naphthalene-2,6-dicarboxylato)diholmium(III)] vol.64, pp.1, 2008, https://doi.org/10.1107/S1600536807064483
  6. -naphthalene-2,6-dicarboxylato)tetraholmium(III)] 1.75-hydrate] vol.64, pp.2, 2008, https://doi.org/10.1107/S1600536808000378
  7. Hydrothermal Syntheses, Structures, and Properties of Three 3-D Lanthanide Coordination Polymers that Form 1-D Channels vol.2004, pp.14, 2004, https://doi.org/10.1002/ejic.200300876
  8. Metal-organic molecular architectures with 2,2′-bipyridyl-like and carboxylate ligands vol.249, pp.5, 2002, https://doi.org/10.1016/j.ccr.2004.07.006