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Acidity Effect on the Catalytic Properties for Phenol Isopropylation


Abstract

Isopropylation of phenol with 2-propanol has been carried out over Na-exchanged ZSM-5 zeolites to determine the effect of catalyst acidity on phenol conversion and product selectivity. The acid type and strength of the catalyst such as Lewis, weak and strong Bronsted acid sites are measured by pyridine adsorbed XPS and the catalytic properties are interpreted in terms of the acid properties. The active site and mechanism for the reaction are suggested based on evidence of study from the reactant adsorbed FT-IR.

Keywords

References

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Cited by

  1. ChemInform Abstract: Acidity Effect on the Catalytic Properties for Phenol Isopropylation. vol.33, pp.13, 2001, https://doi.org/10.1002/chin.200213027
  2. A facile O-alkylation of 2-naphthol over zeolites Hβ, HY, and HZSM5 using dimethyl carbonate and methanol vol.221, pp.2, 2001, https://doi.org/10.1016/j.jcat.2003.09.013
  3. Preparation of highly ordered mesoporous AlSBA-15 and its application to isopropylation of m-cresol vol.235, pp.1, 2005, https://doi.org/10.1016/j.molcata.2005.03.014