DOI QR코드

DOI QR Code

벤치규모 가압유동층연소로에서 석회석에 의한 국내무연탄의 탈황특성

Desulfurization Characteristics of Domestic Anthracite by Limes at Bench Scale Pressurized Fluidized Bed Combustor .

  • 발행 : 2001.10.01

초록

The desulfurization characteristics of anthracite in a bench scale pressurized fluidized bed combustor are investigated. The coal used in the experiment is domestic anthracite from Kangwon Taeback area. The desulphurization experiment is performed with limestone from Chungbuk Danyang. The pressure of the combustor is maintained at 6 atm, and the combustion temperatures are 850, 900, and 950$\^{C}$. The superficial gas velocities are 0.9, 1.1, and 1.3 m/s. The excess air ratio is varied from 5 to 35%. The Ca/S mole ratios are 0.5, 1.5, 2.5 and 4.5 mole. All experiments are executed at 2m bed height. Consequently, SO$_2$ concentration in the flue gas is increased with incresing bed temperature and superficial gas velocity. However SO$_2$ concentration is decreased with incresing excess air ratio and Ca/S mole ratio.

키워드

참고문헌

  1. 이영우, 손재익, 1995, '복합발전용 가압유동층 연소기술,' 화학공업과 기술, 제13권 1호, p. 53
  2. 진경태, 선도원, 이창근, 박재현, 한근희, 배달희, 조성호, 2000, 'Bench Scale 가압유동층 석탄 연소기술 개발,' 1998-C-CC01-P-01, pp. 1-17
  3. 한근희, 오동진, 류정인, 진경태, 2000, '가압 유동층연소로에서 석탄의 연소 및 배가스특성' 대한기계학회논문집B권, Vol. 24(5), pp.677-686
  4. Kunii, D., Levenspiel, O., 1991, Fluidization Engineering, 2nd edition, Butterworth -Heinemann, pp. 68-77
  5. 박승호, 이동우, 1997, '유동층 연소로의 스케일-업을 위한 유동층 내 연료농도분포 해석', 대한기계학회논문집 B권, Vol. 21(6). pp. 747-757
  6. 최정후, 손재익, 한근회, 배달희, 조성호, 1991, '저공해 유연탄보일러 보급확대를 위한 순환유동층기술 개발(I)' 한국에너지기술연구소연구보고서, KE-91009G, pp. 21-27
  7. Leckner, B., 1998, 'Fluidized Bed Combustion: Mixing and Pollutant Limitation,' Prog. Energy Comb. Sci., Vol. 24, pp. 31-61 https://doi.org/10.1016/S0360-1285(97)00021-X
  8. Newby, R. A., Ulerich, N. H., Keaims, D. L., 1980 'A Technique to Project the Sulfur Removal Performence of Fluidized Bed Combustors', Proceeding of the 6th International conference on fluidized bed combustion, p. 803
  9. Howard, J. R., 1983, Fluidized Bed Combustion and Application, Applied Science Pub., New York
  10. Yrjas, K. P., Lisa, K. and Hupa, M., 1993, 'Sulphur Adsortion Capacity of Different Limestones and Dolomites under Pressurized Combustion Conditions,' Proceeding of the 12th International Conference on Fluidized Bed Combustion, p. 265
  11. Sarofim, A., 1994, 'Fluidized Bed Combustion and Emission Control Issues,' International Clean Coal Technology Symp. on PFBC, Kitakyusyu, Japan
  12. M. Alvarez Cuenca, E.J. Anthony, 1995, Pressurized Fluidized Bed Combustion, First edition, Published by Blackie Academic & Professional, an Imprint of Chapman & Hall, pp. 101-120
  13. Lyngfelt, A. and Leckner, B., 1989, 'The Effect of Reductive Decomposition of CaSO4 on Sulphur,' Proceeding of the 10th International conference on fluidized bed combustion, p. 675
  14. Verweyen, N., and Renz, D., 1991, 'Measurements and Modelling of $SO_2$ Emission from a PFBC,' Proceeding of the 11th International conference on Fluidized Bed Combustion. p. 1401
  15. Adanez, J., Labiano, F. G., Abanades, J. C. and Diego, L. F., 1994, 'Methods for Characterization of Sorbents Used in Fluidized Bed Boilers,' Fuel, Vol.73(3), pp. 355-362 https://doi.org/10.1016/0016-2361(94)90087-6
  16. Podolski, W. F., Miller, S.A., 1983, Pressurized Fluidized Bed Combustion Technology, Noyes Data Co., New Jersey
  17. Vogel, G. J., Swift, W.M., Motagna, J.G., 1976, 'Recent ANL Bench-Scale Pressurized Fluidized Bed Studies,' Proceeding of the 4th International Conference Fluidized bed combustion, MITRE Corp. Report, pp. 21-43
  18. Han, K.H., Park, J. H., Ryu J. I. and Jin, G. T., 1999, 'Coal Combustion Characteristics in a Pressurized Fluidized Bed,' Korean J. Chem. Eng. Vol. 16(6), pp. 804-809
  19. 한근희, 강석환, 배성렬, 장효섭, 유호정, 선도원, 류정인, 진경태, 2000, '가압유동층연소로에서 국내무연탄의 연소특성' 화학공학의 이론과 응용, Vol. 6(2), pp. 3525-3529