Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Dyeing of Polypropylene Fibers in Supercritical Carbon Dioxide

초임계 이산화탄소를 이용한 폴리프로필렌 섬유의 염색

  • 조성미 (부산대학교 의류학과) ;
  • 최석철 (부산대학교 의류학과) ;
  • 류진하 (부경대학 생물화학공학과) ;
  • Published : 2001.11.01

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Abstract

PP fiber and fabric were dyed with several disperse dyes without any auxiliaries in SCF-$CO_2$. The solubility of the dyes used and dyeability of PP in SCF-$CO_2$ were investigated. The partition coefficient (K) between PP and SCF-$CO_2$ was calculated at various temperature and pressure. Color fastness of dyed fabrics were also investigated. The solubilites of dyes increased exponentially with increasing $CO_2$density. At constant density, the solubility of dyes increased with rising temperature. The rate of dyeing were very high and almost constant under the different dyeing conditions. The equilibrium dye adsorption increased with rising pressure and temperature dyeing conditions. The equilibrium dye adsorption increased with rising pressure and temperature. It is clearly proved that K decreases with increasing pressure and increases with rising temperature. Log K decreased linearly with $CO_2$density, log $\rho$. Therefore, high affinity of the dye for the fibers in SCF-$CO_2$dyeing system was much differnt from solvent dyeing with extremely small affinity of the dye for the fibers.

Keywords

References

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