RF-enhanced DC-magnetron Sputtering of Indium Tin Oxide

  • Futagami, Toshiro (Now with Osaka National Research Institute) ;
  • Kamei, Masayuki (Now with National Institute for Research in Inorganic Materials) ;
  • Yasui, Itaru (Institute of Industrial Science, University of Tokyo) ;
  • Shigesato, Yuzo (College of Science and Engineering, Aoyama Gakuin University)
  • 발행 : 2001.03.01

초록

Indium tin oxide (ITO) films were deposited on glass substrates at $300^{\circ}C$ in oxygen/argon mixtures by RF-enhanced DC-magnetron sputtering and were compared to those by conventional DC magnetron sputtering. The RF enhancement was performed using a coil above an ITO target. X-ray diffraction measurements revealed that RF-enhanced plasma affected the preferred orientation and the crystallinity of the films. The resistivity of the films prepared by RF-enhanced DC-magnetron sputtering was almost constant at oxygen content lower than 0.3% and then increased sharply with increasing oxygen content. However the resistivity of the films by conventional sputtering has little dependence on the oxygen content. Those results can be explained on the basis of the incorporation of oxygen into the ITO films due to the RF enhancement.

키워드

참고문헌

  1. Appl. Phys. Lett. v.64 no.19 Maskless Patterning of Indium Tin Oxide Layer for Flat Panel Displays by Diode-Pumped Nd:YLF Laser Irradiation M. Takai;D. Bollmann;K. Haberger
  2. J. Appl. Phys. v.69 no.3 Mechanism of Carrier Transport in Highly Efficient Solar Cells Having Indium Tin Oxide/Si Junctions H. Kobayashi;Y. Ishida;Y. Nakato;H. Tshbomura
  3. Thin Solid Films v.263 Preparation and Properties of Transparent Conducting Indium Tin Oxide Films Deposited by Reactive Evaporation H. L. Ma;D. H. Zhang;P. Ma;S. Z. Win;S. Y. Li
  4. Jpn. J. Appl. Phys.Part 2 v.29 no.2 Indium-Tin Oxide Thin Films Prepared by Chemical Vapor Deposition from Metal Acetates T. Maruyama;K. Tabata
  5. Thin Solid Films v.194 no.1-2 Reaction Kinetics of the Formation of Indium Tin Oxide Films Grown by Spray Pyrolysis V. Vasu;A. Subrahmanyam
  6. Appl. Surf. Sci. v.96-98 Pulsed Laser Deposition of High Quaity ITO Thin Films F. Hanus;A. Jadin;L. D. Laude
  7. Appl. Surf. Sci. v.48-49 Crystallinity and Electrical Properties of Tin-Doped Indium Oxide Films Deposited by DC Magnetron Sputtering Y. Shigesato;S. Takaki;T. Haranou
  8. Thin Solid Films v.172 Deposition of Tin-Doped Indium Oxide Films by a Modified Reactive Magnetron Sputtering Process A. A. Karim;C. Deshpandey;H. J. Doerr;R. F. Bunshah
  9. Jpn. J. Appl. Phys. v.33 no.9A Effects of Magnetic Field Gradient on Crystallographic Properties in Tin-Doped Indium Oxide Films Deposited by Electron Cyclotron Resonance Plasma Sputtering E. Kubota;Y. Shigesato;M. Igarashi;T. Haranou;K. Suzuki
  10. J. Vac. Sci. Technol. v.A7 no.2 Fundamental Characteristics of Built-in High-Frequency Coil-Type Sputtering Apparatus M. Yamashita
  11. Appl. Phys. Lett. v.63 no.24 Magneron Sputter Depositon with High Levels of metal Ionization S. M/ Rossnagel;J. Hopwood
  12. submitted to Jpn. J. Appl. Phys. Characterization fo RF Enhanced DC Sputtering to Deposit Tin-Doped Indium Oxide Thin Films T. Futagami;Y. Shigesato;I. Yasui
  13. Acta Cryst v.20 Refinement of the Crystal Structure of In₂O₃at two Wavelengths M. Marezio
  14. Joint Committee on Powder Diffraction Standards Powder Diffraction File; Card 6-0416.
  15. Thin Solid Films v.266 On the Homogeneity of Suptter-Deposited ITO Films. Park I. Stress and Microstructure T. J. Vink;W. Walrave;J. L. C. Daams;P. C. Baarslag;J. E. A. M. van den Meekakker
  16. Appl. Surf. Sci. v.120 Study of the Effect of the Oxygen Partial Pressure on the Properties of RF Reactive Magnetron Sputtered Tin-Doped Indium Oxide Films L. Meng;M. P. dos Santos
  17. App. Phys. v.A27 Electrical Properties and Defect Model of Tin-Doped Indium Oxide Layers G. Frank;H. Kostlin
  18. Semicon. Sci. Technol. v.11 Effect of Oxygen Concentration in the Sputtering Ambient on the Microstructure, Electrical and Optical Properties of Radio-Frequency Magnetron Sputtered Indium Tin Oxide Films W. F. Wu;B. S. Chiou
  19. J. Electrochim. Soc. v.140 no.6 Microstructure and Electrical Characteristics of Sputtered Indium Tin Oxide Films M. Higuchi;M. Sawada;Y. Kuronuma