ESR Spectroscopy for Detecting Gamma-Irradiated Shellfishes

방사선 조사된 조개류의 확인을 위한 ESR Spectroscopy의 이용

  • 남혜선 (한국원자력연구소 식품검지실) ;
  • 양재승 (한국원자력연구소 식품검지실)
  • Published : 2001.02.01

Abstract

Electron spin resonance (ESR) spectroscopy was used to investigate the effect of irradiation dose on the ESR signal intensity and to identify the stability of radicals after 9 weeks of storage in order to detect irradiated shellfishes. The irradiated shellfishes (short-necked clam, purplish washington clam, freshwater clam, jackknifed clam, scallop and hard-shell mussel) presented an asymmetric absorption in shape at $g_{1}$=2.002~2.003 and $g_{2}$=1.998. The strength of the ESR signal increased linearly with the applied doses (1~7 kGy). A highly positive correlation coefficients ($R^{2}$=0.9136~0.9896) were obtained between the irradiation dose and corresponding ESR signal intensity. The intensity of the signals after irradiation was stable even after 9 weeks of storage at 5$\pm$1$^{\circ}C$.

Keywords

References

  1. 국민영양 v.3 방사선 조사식품 변명우
  2. J. Korean Nuclear Society v.30 An alternative technology for an emerging need Yang J. S.
  3. Appl. Radiat. Isot. v.47 ESR detection of irradiated seashells. Raffi, J.;Hasbany C.;Lesgards G.;Ochin D
  4. Cost benefits of aspects of food irrdiation processing Economic benefits of irradiation of molluscan shellfish in Lousiana Kilgren M. B.
  5. Radiat. Phys. Chem. v.42 Identification of irradiated foods by monitoring radiolytically produced hydrocarbons Morehouse K. M.;Ku Y.
  6. JAOCS v.74 Detection of hydrocarbons in irradiated and roasted sesame seeds Choi C. R.;Hwang K. T.
  7. Mutat. Res. v.339 The comet assay;a comprehensive review Fairbairn D. W.;Olive P. L.;O'Neill K. L.
  8. Mutat. Res. v.375 The DNA 'comet assay' as a rapid screening techniques to control irradiated food Cerda H.;Delincee H.;Haine H.;Rupp. H
  9. J. Appl. Bacteriol. v.64 the detection of irradiated foods using the direct epifluorescent filter technique Betts R. P.;Farr L.;Banked P.;Stringer M .F.
  10. Food Sci. Technol v.8 Limulus amoebocyte lysate test/gram negative bacteria count method for the detection of irradiated poultry;Results of two interlaboratory studies Scotter S. L.;Bearwood K.;Wood R.
  11. Radiat. Phys. Chem v.46 Application of half-embryo test to irradiated apples and cherries Kawamura Y.;Miura A.;Sugita T.;Yamada T..;Saito Y.
  12. Detection methods for irradiated foods Development of half-embryo test germination test for detection of irradiated fruits and grains Kawamura Y.;Murayama M.;Uchiyama S.;Saito Y.;Mcmurray C. H.(eds.);Stewary E. M.(eds.);Gray R.(eds.);Pearce J.(eds.)
  13. Radiat Phys. Chem. v.48 Half-embryo test for identification of irradiated citrus fruit;collaborative study Kawamura Y.;Sugita T.;Yamada T.;Saito Y.
  14. Radiat. Phys. Chem. v.42 Detection of irradiated wheat by germination Zhu S.
  15. Food Sci.Technol. v.8 The use of cyclobutanones in the development of an enzyme-linked immunosorbent assay(ELISA) for the detection of irradiated food Hamilton L.;Elliot C. T.;Boyd D. R.;McCaughey W. J.;McEvoy J. D. G.;Stevenson M. H.
  16. Detection methods for irradiated foods The use of 2-substituted cyclobutanones in the development of an enzyme-linked immunosorbent assay (ELISA) for the detection of irradiated foods Hamilton L.;Elliot C. T.;Boyd D. R.;McCaughey W. J.;Stevenson M. H.;McMurray C. H.(eds.);Stewart E. M.(eds.);Gray R.(eds.);Pearce J.(eds.)
  17. Food Sci. Technol v.10 The use of cyclobutanones in the development of an enzyme-linked immunosorbent assay (ELISA) for the detection of irradiated lipid-containing foods Hamilton L.;Elliot C. T.;Boyd D. R.;McCaughey W. J.;Pearce J.
  18. Radiat. Phys. Chem. v.36 Thermoluminscence of irradiated food stuffs Oduko J. M.;Spyrou N. M.
  19. Radiat. Phys. Chem. v.43 Methods for routine controlof irradiated food;determination of the irradiation status shellfish by thermoluminescence analysis Scheiber G. A.;Hoffman A.;Helle N.;Bogl K. W.
  20. Radiat. Phys. Chem. v.48 Variation in thermoluminescence of irradiated brans of food stuffs;A test for hygienic quality Mamoon A.;Zaheer A.;Abu-Abdullah S.
  21. J. Anal. Chem. v.354 Radiolyo-chemiluminescence of bones and seafood shells;A new promissing method for the detection of food irradiation Anderle N.;Steffan I.;Wild E.;Hille P.
  22. A new approach to identifying irradiated foods Photostimilated luminescence(PSL) Sanderson D.
  23. Appl. Magn. Reson. v.10 Electron paramagnetic resonance detection of irradiated foodstuffs Raffi J.;Stocker P.
  24. J. Chem. Phys v.91 Application of ESR to identification of irradiated foodstuffs Raffi J.;Belliardo J. J.;Agnel J. P.
  25. J. Radiat. Ster. v.1 Identification of irradiated foods by electron spin resonance techniques Raffi J. J.;Benzaria S. M.
  26. Appl. Radiat. Isot. v.147 Current status of the ESR method to detect irradiated food Desrosiers. M. F.
  27. New Physico-chemical techniques for the characterization of complex food system Election spin resonance spectroscopy for detection of irradiated food Cray R.
  28. J. Korean Nuclear Society v.29 General survey detection methods for irradiated foods Yang J. S.
  29. Nature v.334 ESR detection of irradiation of irradiated food Dodd N.; Lea J.;Swallow A.
  30. Radiat. Phys. Chem. v.54 TL and ESR signals of molluscan shells correlations and suitability for the detection of irradiated foods Ziegelmann B.;Bogl K. W.;Schreiber G. A.