한국섬유공학회지 (Textile Science and Engineering)

  • 제38권5호
  • /
  • Pages.209-213
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  • 2001
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  • 1225-1089(pISSN)
  • /
  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지

BPO-DMA 레독스 개시계를 이용한 메탄올 중에서 비닐아세테이트 저온 라디칼 용액중합

Low Temperature Radical Solution Polymerization of Vinyl Acetate, Initiated by Benzoyl Peroxide-N, N-dimethylaniline in Methanol

  • 마석일 (인하대학교 공과대학 섬유공학과) ;
  • 이동은 (인하대학교 공과대학 섬유공학과) ;
  • 권순홍 (인하대학교 공과대학 섬유공학과)
  • 발행 : 2001.05.01

⟨ 이전 논문 다음 논문 ⟩

초록

Synthesis of high molecular weight poly9vinyl acetate) with less branched structure has been attempted by solution polymerization of vinyl acetate in methanol at $0^{\circ}C$ using a redox pair of benzoylperoxide-N, N-dimethyl aniline. Although the rate of polymerization is low at this temperature, ply9vinyl acetate) having maximum degree of polymerization of 2800 with degree of branching of 0.125 at 100% conversion was obtained.

키워드

참고문헌

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