Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Low Temperature Radical Solution Polymerization of Vinyl Acetate, Initiated by Benzoyl Peroxide-N, N-dimethylaniline in Methanol

BPO-DMA 레독스 개시계를 이용한 메탄올 중에서 비닐아세테이트 저온 라디칼 용액중합

  • 마석일 (인하대학교 공과대학 섬유공학과) ;
  • 이동은 (인하대학교 공과대학 섬유공학과) ;
  • 권순홍 (인하대학교 공과대학 섬유공학과)
  • Published : 2001.05.01

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Abstract

Synthesis of high molecular weight poly9vinyl acetate) with less branched structure has been attempted by solution polymerization of vinyl acetate in methanol at $0^{\circ}C$ using a redox pair of benzoylperoxide-N, N-dimethyl aniline. Although the rate of polymerization is low at this temperature, ply9vinyl acetate) having maximum degree of polymerization of 2800 with degree of branching of 0.125 at 100% conversion was obtained.

Keywords

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