The Korean Journal of Ceramics

The Korean Ceramic Society (한국세라믹학회)
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Investigation of Lattice Effects in Perovskites by $O-isotope^{18}$ Exchange

  • Itoh, Mitsuru (Materials & Structures Laboratory Tokyo Institute of Technology 4259 Nagatsuta) ;
  • Mahesh, Rajappan (Materials & Structures Laboratory Tokyo Institute of Technology 4259 Nagatsuta) ;
  • Wang, Ruiping (Materials & Structures Laboratory Tokyo Institute of Technology 4259 Nagatsuta)
  • Published : 2000.09.01
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Abstract

In the present study, preliminary experimental results of the change in the properties of perovskite-type oxides caused by the $^{18}O$- exchange have been reported. Two systems were selected for the exchange, (1) $ATiO_3$(A=Ca,Sr,Ba) and (2) manganese perovskite. The dielectric properties of isotope-exchanged $SrTi^{18}O_3$showed a drastic change from a quantum paraelectricity below 3K to ferroelectric-like behavior with a peak at 23K and an enhanced dielectric constant, 35000 at the peak. On the contrary, the $T_c$ for $BaTiO_3$was found to increase by 0.9K. The observed isotope shift of $T_c$ as well as $T_co$ for the manganese perovskites is correlated with the key parameters controlling the lattice such as $Mn^{3+}$ content, average ionic radius of the A-site cation <$r_A$> ad A-site ionic disorder $\sigma^2$.

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References

  1. Phys.Rev v.86 Dielectric Constant in Perovskite-Type Crystals J.H.Barrett
  2. Phys.Rev.B v.19 SrTiO3:An Intrinsic Quantum Paraelectiric Below 4 K K.A.Muller;H.Burkard
  3. J.Solid State Chem v.101 Electrical Conductivity and Metal-Nonmetal Transition in the Perovskite Related Layered System Can+1TinO3n+1-δ(n=2,3 and ∞) I.S.Kim,M.Itoh;Y.Nakamura
  4. J.Phys.Soc.Jpn v.61 Quantum Paraelectricity in a Perovskite La1/2Na1/2TiO3 Y.Inaguma,J.H.Sohn,I.S.Kim,M.Itoh;T.Nakamura
  5. Ferroelectrics v.200 High Temperature Quantum Paraelectricity in Perovskite type La1/2Na1/2TiO3(Ln=Pr,Ne,Sm,Eu,Gd and Td) P.H.Sun,T.Nakamura,Y.J.Shan,Y.Inaguma;M.Itoh
  6. Solid State Ionics v.108 Prepatation and Dielectric Characterization of the Novel perovskite type Oxides La1/2Na1/2TiO3(Ln=Dy,Ho,Er,Tm,Yb,Lu) Y.J.Shan,T.Nakamura,Y.J.,Shan,Y.Inaguma;M.Itoh
  7. Solid State Ionics v.108 The Cause of the High Temperature Quantum Paraelectricity in Some Perovskite Titanate T.Nakamura,Y.J.Shan,P.H.Sun,Y.Inaguma;M.Itoh
  8. Stress induced Ferroelectricity and Soft Phonon Modes in SrTiO3 v.13 H.Uwe;T.Sakudo,
  9. Acta Cryst v.A32 Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides R.D.Shannon,
  10. Phys.Rev.Lett v.52 Sr1-xCaxTiO3 : An XY Quantum Ferroelectric with Transition to Randomness J.G.Bednortz;K.A.Muller
  11. Physica(Utrecht) v.16 Ferromagnetic Compounds of Manganese with Perovskite Structure G.H.Jonker;J.H.Van Santen
  12. Phys.Rev. v.100 Neutron Diffraction Study of the Magnetic Properties of the Series of Perovskite type Compounds[(1-x)La,xCa]MnO3 E.O.Wollan;W.C.Koehler,
  13. Physica(Amsterdam) v.155B Magnetoresistance Measurements of the Magnetic Semiconductor Nd0.5Pb0.5MnO3 R.M.Kusters,J.Singleton,D.A.Keen,R.M.McGreevy;W.Hayes
  14. Nature v.386 Evidence for Magnetic Polarons in the Magnetoresistive Porovskites J.M.De Teresa,M.R.Ibarra,P.A.Algarabel,C.Ritter,C.Marquina,J.Blasco,J.Garcia,A.del Moral ;Z.Arnold
  15. Phys.Rev.Lett v.74 Spiral State and Giant Magnetoresistance in Perovskite Mn Oxides A.J.Millis,P.B.Littlewood;B.I.Shraiman
  16. J.Appl.Phys v.83 Tunneling Evidence of Half metallicity in Epitaxial Films of Ferromagnetic Perovskite Manganites and Ferrimagnitic manganite L.J.Zou,H.Q.Lin;Q.Q.Zheng,
  17. Phys.Rev.Lett v.77 Direct Observation of Lattice Polaron Formation in the Local Structure of La1-xCaxMnO3 S.J.L.Billinge,R.G.Difrancesco,G.H.Kwei,J.J.Neumeier;J.D.Thompson,
  18. Phys.Rev.B v.56 Local Jahn-Teller distortion in La1-xSrxMnO3 Observed by pulsed Neutron Diffraction D.Louca,T.Egami,E.L.Brousha,H.Roder;A.R.Bishop,
  19. Phys.Rev.B v.54 Evidence of Magnetization dependent Polaron Distribution in La1-xAxMnO3 A=Ca,Pb C.H.Booth,F.Bridges,S.J.Snyder;T.H.Geballe,
  20. Phys.Rev.B v.53 Intrinsic Electrical Transport and Magnetic Properties of La0.67Ca0.33MnO3 and La0.67Sr0.33MnO3 MOCVP Thin Films and Bulk Material G.J.Synder,R.Hiskes,S.Dicarolis,M.R.Beasley;T.H.Geballe
  21. Phys.Rev.Lett v.78 Hall-Effect Sign Anomaly and Small Polaron Conduction in (La1-xGdx)0.67Ca0.33MnO3 M.Jaime,H.T.Hardner,M.B.Salamon,M.Rubinstein,P.Dorsey;D.Emin
  22. Nature(London) v.381 Giant Oxygen Isotope Shift in the Magnetoresistive Perovskite La1-xCaxMnO3-x G.M.Zhao,K.Conder,H.Keller;K.A.Muller,
  23. Chem,Mater v.8 Giant Magnetoresistance in Transition Metal Oxides C.N.R.Rao,A.K.Cheetham;R.Mahesh
  24. unpublished work M.Iton et al
  25. Phys.Rev.B v.53 Structure Electron transport Properties and Giant Magnetoresistance of Hole-doped LaMnO3 System R.Mahendiran,S.K.Tiwari,A.K.Raychaudhuri,T.V.Ramakrishnan,R.Mahesh,N.Rangavittal and C.N.R.Rao
  26. Monographs in Condensed Matter Physics S.W.Cheong;H.Y.Hwang,Colossal Magnetoresistance Oxides ,Y.Tokura,Gorden&Breach
  27. (to be published) R.Mahesh;M.Iton
  28. Phys.Rev.Lett v.80 Phonon-Assited Double Exchange in Perovskite Manganites J.S.Zhou;J.B.Goodenough
  29. J.Solid State Chem v.120 Giant Oxygen Istope Shift in the Magnetoresistive Perovskite La1-xCaxzMnO3+y R.Mahesh,R.Mahendiran,A.K.Raychaudhuri;C.N.R.R Ao
  30. Phys.Rev.Lett v.75 Lattic Effects on the Magnetoresistance in Doped LaMnO3 H.Y.Hwang,S.W.Cheong,P.G.Redaelli,M.Marezio;B.Batlogg,
  31. Solid State Commun v.105 Oxygen-Istope Effect on the Field-Induced Metal-Insulator Transition in Pr2/3Ca1/3 MnO3 B.Garcia-Landa,M.R.Ibarra,J.M.DeTeresa,G.M.Zhao,K.Conder;H.Keller
  32. Phys.Rev.B v.54 Cation Disorder and Size Effects in Magnetoresistive Manganese Oxide Perovskites L.M.Rodriguez-Martinez;J.P.Attfield