Effect of Curing Agent Content on the Thermal and Physical Properties of Conductive Ag/Epoxy System

경화제 조성 변화에 따른 도전성 Ag/에폭시 조성물의 열적 특성 및 물성에 관한 연구

  • 전병철 (수원대학교 고분자공학과) ;
  • 이성재 (수원대학교 고분자공학과) ;
  • 차상혁 (수원대학교 고분자공학과) ;
  • 배규식 (수원대학교 전자재료공학과) ;
  • 박성용 ((주)창성 중앙연구소) ;
  • 정인범 ((주)창성 중앙연구소)
  • Published : 2000.12.01

Abstract

The effect of composition and curing temperatures on the thermal stability and adhesive strength of an Ag/epoxy conductive adhesive, currently being used in IC(integrated circuit) and PCB(printed circuit board) packaging, are investigated. DSC thermogram results indicate that the cure time is shrotened when curing agent is introduced in excess to the epoxy system. At the same curing temperature, higher degree of cure is obtained as the 4,4'-diaminodiphenyl sulfone(DDS) content is increased. This also influences the heat deflection temperatur and adhesive strength of the prepared epoxy compositions. From this investigation, the optimum epoxy composition is obtained at higher than 30 phr of DDS and curing temperatures above 150℃. Lastly, Ag flakes are introduced to raise the conductivity, and a diluent to reduce the viscosity of the adhesive. As a result, the electrical conductivity of Ag/epoxy system is increased about $10^{12}$ times higher than that of epoxy system.

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