UV Emission Characterization of ZnO Thin Films Depending on the Variation of Oxygen Pressure

분위기 산소압변화에 따른 ZnO박막의 UV발광 특성분석

  • Published : 2000.02.01

Abstract

ZnO is a wide-bandgap II-IV semiconductor and has a variety of potnetial applications. ZnO exhibits good piezoelectric, photoelectric and optical properties, and is a good candidate for an electroluminescence device. ZnO films have been deposited on (001) sapphire by PLD technique. Nd:YAG pulsed laser was operated at a wavelength of $\lambda=355nm$. The ZnO films were deposited at oxygen pressures from base to 500 mTorr. The substrate temperatures was increased from $200^{\circ}C\; to\;700^{\circ}C$ films showed strong UV emission by increasing the partial oxygen pressure. We have investigated the relationship between partial oxygen pressure and the intensity of UV emission.

Keywords

References

  1. 심경석, 이상렬, '레이저 증착변수에 의한 다이아몬드상 카본박막 특성 변화,' 대한전기학회논문지, Vol. 48, No.5, 344-348, 1999
  2. Y.S. Jeong, S.Y. Lee, H.K. Jang, I.S. Yang, S.H. Moon and B.D. Oh, 'Surface modification of laser ablated YBCO target,' Applied Surface Science, vol.109, 424-427, 1997 https://doi.org/10.1016/S0169-4332(96)00778-7
  3. Y. Chen, D.M. Bagnall, Z. Zhu, T. Sekiuchi, K. Park, K. Hiraga, T. Yao, S. Koyama, M.Y. Shen, T. Goto, 'Growth of ZnO single crystal thin films on c-plane(001) sapphire by plasma enhanced molecular beam epitaxy,' Journal of Crystal Growth, 181, 165, 1997 https://doi.org/10.1016/S0022-0248(97)00286-8
  4. K.B. Sundaram, A. Khan, 'Characterization and optimization of zinc oxide films by r.f. magnetron sputtering,' Thin Solid Films, 295, 87, 1997 https://doi.org/10.1016/S0040-6090(96)09274-7
  5. B.M. Atev, A.M. Bagamadova, V.V. Mamedov, 'On exciton luminescence of $ZnO/Al_2O_3$ epitaxial thin films,' Thin Solid Films, 283, 5, 1996 https://doi.org/10.1016/0040-6090(96)08826-8
  6. D.C. Reynolds, D.C. Look, B. Jogai, J.E. Van Nostrand, R. Jones and J. Jenny, 'Source of the Yellow luminescence band in GaN by gas-source molecular beam epitaxy and the green luminescence band in single crystal ZnO,' Solid State Communications, Vol. 106, No. 10, pp. 701-704, 1998 https://doi.org/10.1016/S0038-1098(98)00048-9
  7. H. J. Egelhaaf, D. Oelkrug, 'Luminescence and nonradiative deactivation of excited states involving oxygen defect centers in polycrystalline ZnO,' Journal of Crystal Growth, Vol. 161, p. 192, 1996 https://doi.org/10.1016/0022-0248(95)00634-6
  8. Simon L. King, J.G.E. Gardeniers, Ian W. Boyd, 'Pulsed-laser deposited ZnO for device applications,' Applied Surface Science 96-98, 811, 1996 https://doi.org/10.1016/0169-4332(96)80027-4
  9. 이용의, 김형준, 양형국, 박순섭, 박종철, 김영진, 'ZnO박막과 유전체 박막으로 구성된 이중구조의 물성 및 표면 탄성파 측정,' Korean J. Cryst. Vol. 6, No. 2, pp. 134-140, 1995
  10. 김영진, 권오준, 유상대, 김기완, '고주파 마그네트론 스펏터링법으로 제조한 ZnO박막의 기판에 따른 효과,' 센서학회지, 제5권, 제6호, pp. 68-73, 1996
  11. 김영진, 권오준, 유상대, 김기완, '고주파 마그네트론 스펏터링법으로 제조한 ZnO박막의 기판에 따른 효과,' 센서학회지, 제5권, 제6호, pp. 68-73, 1996
  12. C. Kittel, 'Introduction to Solid State Physics,' John Wiley & Sons, Inc., New York, 7th ed, p. 58, 1996
  13. D. B. Chrisey, G. K. Hubler, 'Pulsed laser deposition of thin films,' John Wiley & Sons, Inc. New York, 1st ed. chapter 6, 1994
  14. J. Lee, J. Song, 'A study on c-axis preferred orientation at a various substrate temperature of ZnO thin film deposited by rf magnetron sputtering,' J. Korean Institute of Electrical and Electronic Material Engineers, Vol. 9, No. 2, pp. 196-203, 1996
  15. S. A. Studeninkin, N. Golego and M. Cocivera, 'Fabrication of green and orange photoluminescent, undoped ZnO films using spray pyrolysis,' J. Appl. Phys., Vol. 84, No. 4, pp. 2287-2294, 1998 https://doi.org/10.1063/1.368295
  16. K. Vanheusden, C.H. Seager, W.L. Warren, D.R. Tallant, J.A. Voigt, 'Correlation between photoluminescence and oxygen vacancies in ZnO Phosphors,' Appl. Phys. Lett. 68 (3), 15, pp. 403-405, 1996 https://doi.org/10.1063/1.116699