Abstract
$\varepsilon$-Caprolactame as organic monomer was intercalated in the interlayer space of montmorillonite and polymerized by polymerization reaction so that the inorganic polymer and organic polymer could be combined each other by chemical bonding. The results of X-ray and IR analysis showed that the polymerization reaction of $\varepsilon$-caprolactame between the interlayer spaces has been performed sucessfully. In order to study polymeric reaction product in detail we have isolated the polymerized material from the interlayer space and analyzed it by X-ray diffractometer and IR-Spectrocopy. The comparison of these results with them of the analyses for thee pure polymer which has been synthesized by polymeric reaction of $\varepsilon$-carolactame without montmorillonite showed that the obtained both polymeric materials are the same compounds.
유기단분자인 $\varepsilon$-Caprolactame을 montmorillonite의 층사이에 삽입하여 증합반응시켜 고분자화해 줌으로써 무기고분자와 유기고분자를 화학결합에 의해 연결시켜 주었다. X-선 및 IR-분석결과 층내에서의 $\varepsilon$-Caprolactame의 고분자반응이 성공적으로 이루어졌음이 입증되었다. 고분자 반응생성물을 좀 더 자세히 분석조사하기 위해 고분자 물질을 층사이로부터 격리시켜 X-선회절분석 및 IR 분석한 결과와 montmorillonite없이 $\varepsilon$-Caprolactame만 고분자화시켜 얻은 순수고분자에 대한 동일한 분석 결과를 비교해 본 결과 서로 동일한 화합물임이 입증되었다.
