Microstructure and Properties of Nano-Sized Ni-Co Particulate Dispersed $Al_2O_3$ Matrix Nanocomposites

  • Oh, Sung-Tag (Fine Ceramics Research Association) ;
  • Mutsuo Sando (National Industrial Research Institute of Nagoya) ;
  • Koichi Niihara (The Institute of Scientific and Industrial Research, Osaka University)
  • Published : 1998.12.01

Abstract

In purpose of introducing the inverse magnetostrictive properties into the structural ceramics, $Al_2O_3$ based nanocomposites dispersed with nano-sized Ni-Co particles were studied. The composites were fabricated by the hydrogen reduction and hot-pressing of $Al_2O_3$ and NiO-CoO mixed powders. The mixtures were prepared by using Ni- and Co-nitrate $(Ni(NO_3)_2\;{\cdot}\;6H_2O\;and\;Co(NO_3)_2\;{\cdot}\6H_2O)$ as source materials for the Ni-Co particles. Microstructural observations revealed that nano-sized Ni-Co particles were dispersed homogeneously at $Al_2O_3$ grain boundaries. High strength above 1 GPa was obtained for the $Al_2O_3/10$ wt% Ni-Co nanocomposite fabricated by a controlled powder preparation process. The inverse magnetostrictive response to applied stress was obtained due to the presence of dispersed Ni-Co particles, which indicates a possibility to incorporate new functions into the structural ceramics without loosing the mechanical properties.

Keywords

References

  1. J.Ceram. Soc. Jpn. v.99 K.Niihara
  2. Francture Mechanics of Ceramics v.9 A.Nakahra;K.Niihara;M.Sasaki(ed.);R.C.Bradt(ed.);D.P.H.Hasselman(ed.);D.Munz(ed.)
  3. J.Mater.Sci. v.32 T.Sekino;K.Niihara
  4. J. Europ. Ceram. Soc. v.18 no.31 S.-T.Oh;T.Sekino;K.Niihara
  5. J.Am.Ceram.Soc. v.80 T.Sekino;T.Nakajima;S.Ueda;K.Nuuhara
  6. J.Metals v.23 B.D.Cullity
  7. Proceedinfs of the 14th International Japan-Korea Semitor on Ceramics M.Awano;M.Sando;K.Niihara
  8. Materials Science and Technology v.3B J.R.Cullen;A.E.Clark;K.B.Hathaway;K.H.J. Buschow(ed.)
  9. Ceramics v.32 M.Awano
  10. J.Am.Seram.Soc v.80 Y.-K Jeong;A.Nakahira;P.E.D.Morgan;K.Niihata
  11. Nanostruct.Mater v.10 no.31 S.-T.Oh;T.Sekino;K.Niihara
  12. Introduction to Ceramics(2nd ed) W.D.Kingery;H.K.Bowen;D.R.Uhlmann
  13. Mater. Sci. Res. v.15 M.P.Harmer;S.J.Bennison;C.Narayan
  14. Scripta Mater. v.39 S.-T.Oh;M.Sando;K.Niihara
  15. Introduction to Magnetic Materials B.D.Cullity