The Korean Journal of Ceramics

한국세라믹학회 (The Korean Ceramic Society)
권호 표지

DC Electrical Current Behavior of Calcia Doped Zirconia Under Various Oxygen Containing Gases

  • Lee, Joo-Sin (Department of Materials Science and Engineering, Kyung-Sung University) ;
  • Park, Tae-Woon (Department of Materials Science and Engineering, Kyung-Sung University)
  • 발행 : 1997.03.01
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초록

The DC current variation of calcia doped zirconia single crystal was measured under various oxygen containing gases at high temperatures. The DC current was influenced by the gas species for oxygen activity establishment. Also, strong non-ohmic characteristics were observed in the $CO/CO_2/N_2$ gas mixtures. Based on the experimental data obtained by introducing the non-buffering gas $N_2$ into the $CO/CO_2$ mixtures, the processes occurring at the gas/solid interface during a defect relaxation process are discussed.

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참고문헌

  1. in Advances in Ceramics-Science and Technology of zirconia H. Schmalzried;A. H. Heuer(ed);L. W. Hobbs(ed);
  2. J. Chem. Soc. v.86 Demixing, Decomposition and Degradation of Oxides in Chemical Potential Gradients H. Schmalzried
  3. Z. Naturf. v.34a Crystalline Oxide Solid Solution in Oxygen potential Gradients H. Schmalzried;W. Laqua;P. L. Lin
  4. in Fast Ion Transport in Solids S.Pizzini;W.van Gool(ed.)
  5. in Mass Transport in Oxides L. Heyne;J. B. Wachtman, Jr(ed.);A. D. Franklin(ed.)
  6. Electroanalytical Chemistry v.6 D. O. Raleigh;A. J. Bard(ed.)
  7. Electrode Processes in Solid State Ionics M. Kleitz;J. Dupuy(eds.)
  8. Solid Electrolytes R. M. Dell;A. Hooper;P. Hagenmuller(ed);W. van Gool(ed)
  9. Electrochim. Acta. v.8 Elektrochemische Oxydation von Kohlenwasserstoffen in einer Festelektrolybrennstoffzelle bei Temperaturen von 900~1000°C H. Binder;A. Kohling;H. Krupp;K. Pichter;G. Sandstede
  10. Electrochim. Acta. v.9 S. V. Karpachev;A. T. Filyaev;S. F. Palguev
  11. Z. Chem. v.6 Sauerstoffionenleitende Festelektrolyte und ihre Anwendungsmoglichkeiten H.-H. Mobius;B. Rohland
  12. J. Electrochem. Soc. v.117 direct Current-Voltage Characteristics of Calcia Stabilized Zirconia with Porous Platinum Electrodes H. Yanagida;R. J. Brook;F. A. Kroger
  13. J. Electrochem. Soc. v.118 Platinum Electrodes and Calcia-Stabilized Zirconia R. J. Brook;W. L. Pelzmann;F. A. Kroger
  14. J. Electrochem. Soc. v.118 Overpotential Behavior of Stabilized Zirconia Solid Electrolte Fuel Cells T. H. Etsell;S. N. Flengas
  15. J. Solid State Chem. v.5 Sur I'Utilisation D'une Electrode Ponctuelle dans les Cellules a Ozyde Electrolyte Solide P. Fabry;M. Kleitz;C. Deportes
  16. Electroanalytical Chem. and Interfacial Electrochem. v.57 Influence of the Metal and the Electrolyte Composition on the Characteristics of the Oxygen Electrode Reaction on Solid Oxide Electrolyte P. Fabry;M. Kleitz
  17. J. Electrochem. Soc. v.123 Electrochemical Semipermeability and the Electrode Microsystem in Solid Oxide Electrolyte Cells J. Fouletier;P. Fabry;M. Kleitz
  18. Proc. Brit. Ceram. Soc. v.19 L. Heyne and N. M. Beekmans
  19. J. Electrochem. Soc. v.114 Mixed Conduction in Z$r_{0.85}$C$a_{1.85}$$O_{1.85}$ and T$h_{0.85}$$Y_{0.15}$$O_{1.925}$ Solid Electrolytes J. W. Patterson;E. C. Bogren;R. A. Rapp
  20. J. Electrochem. Soc. v.118 J. W. Patterson