Ion Beam Assisted Crystallization Behavior of Sol-Gel Derived $PbTiO_3$ Thin Films

  • Oh, Young-Jei (Division of Ceramices, Korea Institute of Science and Technology) ;
  • Oh, Tae-Sung (Dept. of Metallurgy and materials Science, Hong Ik University) ;
  • Jung, Hyung-Jin (Division of Ceramics, Korea Institute of Science and Technology)
  • Published : 1996.03.01

Abstract

Ion beam assisted crystallization behavior of sol-gel derived $PbTiO_3$ thin films, deposited on bare silicon(100) substrates by spin-casting method, has been investigated. Ar ion bombardment was directly conducted on the spincoated film surface with or without heating the film from room temperature to $300^{\circ}C$. Ion dose was changed from $5{\times}10^{15}$ to $7.5{\times}10^{16}$ $Ar^-/cm^2$. Formation of (110) oriented perovskite phase was obseerved with ion dose above $5{\times}10^{16}\; Ar^+/cm^2$. Crystallization of $PbTiO_3$ thin film could be enhanced with increasing the Air ion dose, or heating the substrate during ion bombardment. Crystallization of the $PbTiO_3$ films by ion bombardment was related to the local heating effect during ion bombardment.

Keywords

References

  1. J. Appl. Phys. v.71 Crystallization of Sputtered Lead Zircornate Titanate Films by Rapid Thermal Processing C. V. R. Vascant Kumar;R. Pascual;M. Sayer
  2. Proc. 9th IEEE, ISAF'94 Preparation and Properties of Lantanium Modified PbTiO₃ Thin Films by rf-Magnetron Sputtering K. Iijima;T. Takeuchi;N. Nagao;R. Takayama;I. Ueda
  3. Mat. Res. Soc. Symp. Proc. v.361 MOCVD of Ferroelectric Pb(Zr,Ti)O₃ Thin Films for Memory Device Applicatins M. Shimizu;T. Shiosaki
  4. Mat. Res. Soc. Symp. Proc. Ferroelectric Pb(Zr,Ti)O₃ Thin Films Prepared by Metalorganic Chemical Deposition Z. C. Feng;B. S. Kwak;A. Ebril
  5. Ceram. Trans. v.25 Processing and Electrical Characterization of Ion Beam Sputter-Deposited PZT Thin Films H. N. Al-Shareeg;K. D. Gifford;M. S. Ameen;S. H. Rou;P. D. Hren;O. Auciello;A. I. Kingon
  6. Mat. Res. Soc. Symp. Proc. v.271 Optimization of Sol-Gel Derived PZT Thin Films by the Incorporation of Excess PbO G. Teowee;J. M. Boulton;D. R. Uhlmann
  7. Ceram. Trans. v.25 Sol-Gel Ferroelectric Films for Optical Waveguides S. D. Ramamurthi;S. L. Swartz;J. R. Busch;V. E. Wood
  8. Mat. Res. Soc. Symp. Proc. v.72 The Effect of Hydrolysis Conditions on the Characteristcis of PbTiO₃ Gels and Thin Films K. D. Budd;S. K. Dey;D. A. Payne
  9. Proc. 9th IEEE, ISAF '94 Preparation and Characterizatin of Manganese Doped Lead Titanate Films by Sol-Gel Techniques R. P. Tandon;V. Raman;R. Singh;A. K. Narula
  10. Mat. Res. Soc. Symp. Proc. v.220 Lead Zircornate Titanate Films Produced by Pulsed Laser Deposition K. L. Saenger;R. A. Roy;K. F. Etzold;J. J. Cuomo
  11. Mat. Res. Soc. Symp. Proc. v.361 Rapid Thermal Processing and Crystallization Kinetics in Lead Zircornate Titanate (PZT) Thin Films E. M. Griswold;L. Weaver;I. D. Calder;M. Syaer
  12. Mat. Res. Soc. Symp. Proc. v.180 Ion-Implantation Effects on Spin-on-Glass (Sol-Gel) SiO₂ Films Y. Shacam-Diamon;N. Moriya;R. Kalish
  13. J. Am. Ceram. Soc. v.76 Ion-Beam-Induced Densification of Zircornia Sol-Gel Thin Films T. E. Levine;J. L. Keddie;P. Revesz;J. W. Mayer;E. P. Giannelis
  14. Handbook of Sputter Deposition Technology: Principles, Technology and Application K. Wasa;S. Hayakawa
  15. Nucl. Instrum. Methods B v.7;8 W. L. Johnson;Y.-T. Cheng;M. van Rossum;M. A. Nicolet