Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Generalization of Keesom Transformation in Multipole-Multipole Interaction Potentials

  • Published : 1995.10.20
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Abstract

In order to ease the treatment of anisotropic potential when developing the variational RRKM theory, we applied Fano-Racah's recoupling theory to the multipole-multipole interaction, resulting in the great simplification of the anisotropic potentials. The treatment appears as a generalization of Keesom transformation in case of dipole-dipole interaction and provides us with great insights to the characteristics of tensorial interactions in the multipole-multipole interaction system.

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References

  1. Prog. React. Kinet. v.12 Howard, M. J.;Smith, I. W. M.
  2. Ber. Bunsenges. Phys. Chem. v.78 Quack, M.;Troe, J.
  3. ibid v.81 Quack, M.;Troe, J.
  4. J. Chem. Phys. v.79 Troe, J.
  5. J. Chem. Phys. v.83 Wardlaw, D. M.;Marcus, R. A.
  6. J. Phys. Chem. v.90 Wardlaw, D. M.;Marcus, R. A.
  7. J. Chem. Phys. v.92 Klippenstein, S. J.;Marcus, R. A.
  8. Research Review of Science and Engineering v.12 Lee, C. W.
  9. Mol. Phys. v.53 Clary, D. C.
  10. Communications from the Physical Laboratory of the University of Leiden, no.SUP. 24b Keesom, W. H.
  11. Irreducible tensorial sets Fano, U.;Racah, G.
  12. Angular momentum in Quantum Mechanics Edmonds, E. R.
  13. The Theory of Atomic Spectra Condon, E. U.;Shortley, G. H.