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Theoretical Investigation on the Effects of Additive Oxygen in HF Chemical Laser Performance

  • Sung-Ho Kim (Department of Chemistry, Soonchunhyang University) ;
  • Ung-In Cho (Department of Chemistry, Yonsei University)
  • Published : 1994.09.20

Abstract

The effect of oxygen for the HF chemical laser performance has been theoretically investigated. Due to the inhibition mechanism of $O_2$ in $H_2$/$F_2$ chain reaction, the rate for the formation of HF is reduced by the addition of $O_2$. As the concentration of $O_2$ in the reaction mixture increases, the pulse power and temperature of the system becomes lower, while total output energy does not change significantly. But addition of $O_2$ makes the system easy to be controlled and the composition of $H_2$+$F_2$ can be high at constant total pressure. With this system, it is possible to obtain higher output energy than oxygen free environment.

Keywords

References

  1. J. Chem. Phy. v.47 Kompa, K. L.;Piementel, G. C.
  2. Chemical Lasers Basov, N. G.;Bashkin, A. S.;Igoshin, V. I.;Oraevsky, A. N.;Shicheglov, V. A.
  3. Handbook of Chemical Laser Suchand, S. N.;Airey, J. R.
  4. IEEE J. Quent. Electron. v.QE-9 Suchand, S. N.;Sutton, D. G.
  5. J. Quant. Electron v.15 Bravyl, B. G.;Vasilev, G. K.;Kiryanov, Sov.
  6. J. Phys. Chem. v.72 Levy, J. B.;Copland, B. K. W.
  7. IEEE J. Quant. Electro. v.QE-9 Kerber, R. L.;Ching, A.;Lundquist, M. L.;Whiyyier, J. S.
  8. J. Chem. Phys. v.73 Taylor, R. L.;Levis, P. F.;Croin, J.
  9. J. Appl. Phys. v.61 Dreiling, T. D.
  10. J. Kor. Chem. Soc. v.33 Kim, Y. M.;Kim, U.;Cho, U. I.
  11. J. Opt. Soc. Kor. v.2 You, M. A.;Cho, U. I.;Kim, S. H.
  12. IEEE J. of Quant. Electron. v.QE-11 Chen, H. L.;Daugherty, J. D.;Fyfe. W.
  13. J. Chem. Phys. v.62 Sullivan, J. H.;Feber, S. C.;Starner, J. W.
  14. J. Appl. Phys. v.49 Frank, K. Truby

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