The Properties of the Metal Hydride electrodes prepared by Silicon Sealant

Si-sealant를 이용하여 제조한 금속수소화물 전극의 특성

  • CHOI, Jeon (Dept. of Metallurgical Eng., Chonnam National University) ;
  • PARK, Choong-Nyeon (Dept. of Metallurgical Eng., Chonnam National University)
  • 최전 (전남대학교 금속공학과) ;
  • 박충년 (전남대학교 금속공학과)
  • Published : 1993.12.31

Abstract

The $(LM)Ni_{4.5}Co_{0.1}Mn_{0.2}Al_{0.2}$ hydrogen storage alloy powders were conducted 25wt% electroless copper plating in an acidic bath. For the preparation of a hydride electrodes, the copper coated alloy powder was mixed with Si-sealant(organosilicon) and compacted with $6t/cm^2$ at room temperature. The electrode characteristics were examined through electrochemical measurements in a half cell. As a sealant contents increased, the initial discharge capacity of si-sealant bounded electrode was lower and the activation rate in high current density was slower. For extended cycles, however, the electrodes with the Si-sealant were superior in a high rate discharge and useful range of temperature over the sealant-free electrode. In addition, the cycle life increased with increasing the amount of Si-sealant added. It can be suggested from the results that the Si-sealant as a binder could be applied to the preparation of the metal hydride electrode.

Keywords