DOI QR코드

DOI QR Code

Development of New High Temperature Plasma Sources for Spectrochemical Analysis: Multivariate Optimization by the Modified Sequential Simplex Method

  • Lee, Gae-Ho (Department of Chemistry, Chungnam National University)
  • 발행 : 1993.04.20

초록

The new high temperature plasma source for spectrochemical analysis has been developed and characterized. In the development of new high temperature plasma sources for atomic emission spectrocopy, optimization of experimental variables is necessary to achieve the best analytical results. By means of a modified sequential simplex optimization method, six experimental variables were optimized. The line-to-background (L/B) ratio for Ca(II) at 393.37 nm was used as measure of the response function. The optimal experimental conditions were found to be at a current of 27.8 A, a plasma length of 28.8 mm, a sample uptake rate of 1.3 ml/min, a sample carrier gas flow rate of 0.7 ml/min, a plasma gas flow rate of 4.9 l/min, and an observation height of 6.4 mm above the top quartz tube.

키워드

참고문헌

  1. Appl. Spectrosc. v.29 D. W. Golightly;J. L. Harris
  2. Appl. Spectrosc. v.31 C. D. Keirs;T. J. Vickers
  3. Anal. Chem. v.50 S. R. Ellebracht;C. M. Fairless;S. E. Manahan
  4. Spectrochim. Acta v.34B G. W. Johnson;H. E. Taylor;R. K. Skogerboe
  5. Spectrochim. Acta. v.35B R. J. Decker
  6. Analyst v.89 S. Greenfield;I. Ll. Jones;C. T. Berry
  7. Anal. Chem. v.37 R. H. Wendt;V. A. Fassel
  8. Appl. Spectrosc. v.24 S. E. Valente;W. G. Schrenk
  9. Spectrochim. Acta v.35B R. J. Decker
  10. Spectrochim. Acta v.43B G. H. Lee;J. P. Shields;E. H. Piepmeier
  11. Spectrochim. Acta v.43B G. H. Lee;J. P. Shields;E. H. Piepmeier
  12. Appl. Spectrosc. v.42 J. P. Shields;Gae H. Lee;E. H. Piepmeier
  13. Anal. Chem. v.46 S. L. Morgan;S. N. Deming
  14. Anal. Chem. Acta v.115 L. Ebdon;M. R. Cave;D. J. Mowthorpe
  15. Anal. Chim. Acta v.113 S. Greenfield;D. T. Burns
  16. Computer J. v.7 J. A. Nelder;R. Mead
  17. Anal. Chem. v.45 S. N. Deming;S. L. Morgan
  18. Anal. Chim. Acta v.73 L. A. Yarbro;S. N. Deming
  19. Anal. Chem. v.53 A. E. Brookes;J. J. Leary;D. W. Golightly
  20. Theory of Spectrochemical Excitation P. W. J. M. Boumans

피인용 문헌

  1. Sequential Simplex Optimization - An Update vol.32, pp.2, 1993, https://doi.org/10.1080/00032719908542815