Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Cross Interaction Constants As a Measure of the Transition State Structure (Part VI). Nucleophilic Substitution Reactions of Benzyl Chlorides with Anilines and Benzylamines

  • Published : 1988.12.20
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Abstract

Results of kinetic studies on the reactions of benzyl chlorides with anilines and benzylamines are reported. Analyses of the cross interaction constants relevant to the degree of bond formation, ${\rho}_{XY}$ and ${\lambda}_{XY}$, are carried out. The magnitudes of the two parameters indicated that the degree of bond formation in the transition state is the typical of that expected for an $S_N2$ reaction, but the reactions with benzylamines appear to have a slightly less degree of bond formation compared with the reactions with anilines.

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